Reactions of low-valent metal complexes with fluorocarbons. Part IX. Iridium and platinum complexes of bis(trifluoromethyl) thioketen and 1,1-bis(trifluoromethyl)ethene-2,2-dithiolate

1970 ◽  
pp. 944 ◽  
Author(s):  
M. Green ◽  
R. B. L. Osborn ◽  
F. G. A. Stone
Keyword(s):  
Metal Complexes ◽  
Platinum Complexes ◽  
Low Valent

Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity

2021 ◽  
Author(s):  
Rong Zhang ◽  
Yanchao Wang ◽  
Yanxia Zhao ◽  
Carl Redshaw ◽  
Igor L. Fedushkin ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Small Molecule ◽  
Main Group ◽  
Group Metal ◽  
Diimine Ligands ◽  
Main Group Metal ◽  
Metal Metal ◽  
Low Valent

The use of dad (and bian) ligands in the stabilization of main-group complexes, in particular metal–metal-bonded compounds, as well as the small molecule reactivity of these (low-valent) metal complexes, is summarized.

Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal–carbon bonds

2019 ◽  
Vol 55 (88) ◽  
pp. 13263-13266 ◽  
Author(s):  
Jade I. Fostvedt ◽  
Trevor D. Lohrey ◽  
Robert G. Bergman ◽  
John Arnold
Keyword(s):  
Metal Complexes ◽  
Structural Diversity ◽  
Carbon Bonds ◽  
Low Valent

Put the methyl to the metal: hydrogenolysis of metal–carbon bonds offers controlled access to low-valent early metal complexes.

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