Transition-metal complexes of the 1,2-dipyridylethylene isomers. Part IV. Far-infrared spectra (450–80 cm.–1) of cobalt(II), nickel(II), and copper(II) halide derivatives

1969 ◽  
Vol 0 (0) ◽  
pp. 2923-2927 ◽  
Author(s):  
M. Brierley ◽  
W. J. Geary ◽  
M. Goldstein
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Infrared Spectra ◽  
Far Infrared ◽  
Far Infrared Spectra

Synthesis and infrared spectra of some transition metal complexes of α-amino acid esters

1967 ◽  
Vol 20 (4) ◽  
pp. 675 ◽  
Author(s):  
RW Hay ◽  
LJ Porter
Keyword(s):  
Amino Acid ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Infrared Spectra ◽  
Metal Ion ◽  
Amino Acid Esters ◽  
Visible Spectra ◽  
Metal Ratio ◽  
Acid Esters

A variety of transition metal complexes of a-amino acid esters have been synthesized, and characterized by analysis, conductivity measurements, and infrared spectra. The complexes can be broadly divided into two groups: (a) complexes in which only a metal-nitrogen bond occurs with the α-amino group of the ester, and (b) complexes in which chelate ring formation occurs via secondary donor groups on the ligand. These latter complexes are found with methyl L-histidinate, methyl γ-glutamate, and methyl L-cysteinate. With the exception of a methyl tryptophanate complex, the infrared spectra show that there is no interaction between the carbonyl group of the ester and the metal ion. The visible spectra of aqueous solutions of the esters and copper(II) at a ligand/metal ratio of 5 : 1 have maxima in the 600-650 mμ range at pH 7 consistent with copper-nitrogen bonding only.

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