Antiferromagnetism in transition-metal complexes. Part I. Metal–metal bonding and spin exchange in binuclear copper(II) complexes

1969 ◽  
Vol 0 (0) ◽  
pp. 2816-2820 ◽  
Author(s):  
R. W. Jotham ◽  
S. F. A. Kettle
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Spin Exchange ◽  
Binuclear Copper ◽  
Metal Bonding ◽  
Metal Metal

Planare Dicarbonylrhodium(I)- und -iridium(I) -Komplexe mit polarisierbaren aromatischen Liganden / Planar Dicarbonylrhodium(I) and Iridium(I) Complexes with Polarizable Aromatic Ligands

1973 ◽  
Vol 28 (3-4) ◽  
pp. 164-167 ◽  
Author(s):  
Rolf Aderjan ◽  
Hermann Breer ◽  
Heimo J. Keller ◽  
Herbert H. Rupp
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
General Type ◽  
Analytical Data ◽  
Metal Interactions ◽  
Metal Metal ◽  
Pmr Spectra

Some new transition metal complexes of the general type M(CO)2(L-L), where M stands for Ir(I), Rh(I) and L-L for a bidentate mononegative ligand are described. They were characterized by means of analytical data and their IR and PMR spectra. The chemical and solid state properties of these compounds are related to the strength of the intermolecular metal-metal interactions.

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