Bridge-splitting reactions and far-infrared spectra of diene derivatives of palladium(II) and platinum(II) complexes

Author(s):  
Bruno Crociani ◽  
Paolo Uguagliati ◽  
Tristano Boschi ◽  
Umberto Belluco
1974 ◽  
Vol 52 (11) ◽  
pp. 2021-2028 ◽  
Author(s):  
C. Preti ◽  
G. Tosi ◽  
D. De Filippo ◽  
G. Verani

Cobalt(II) and nickel(II) halide complexes with thiomorpholin-3-thione and thiazolidine-2-selenone have been prepared. Infrared and far infrared spectra, electronic spectral studies, and magnetic susceptibility measurements indicate that the cobalt derivatives are tetrahedral in structure, nickel chloro- and bromo-thiomorpholin-3-thione derivatives are octahedral while [Nits2I2] and all nickel thiazolidine-2-selenone complexes have a pseudo-tetrahedral symmetry. The probable site of bonding in the ligands is nitrogen in all the complexes studied here, except the nickel derivatives of thiazolidine-2-selenone. These results are confirmed by n.m.r. measurements. Spectroscopic parameters for the complexes have been calculated and compared against similar chromophores containing MN2X2 and MS2X2 chromophores.


1987 ◽  
Vol 36 (1) ◽  
pp. 846-849 ◽  
Author(s):  
G. A. Thomas ◽  
H. K. Ng ◽  
A. J. Millis ◽  
R. N. Bhatt ◽  
R. J. Cava ◽  
...  

1996 ◽  
Vol 54 (14) ◽  
pp. 9775-9783 ◽  
Author(s):  
E. I. Kamitsos ◽  
Y. D. Yiannopoulos ◽  
H. Jain ◽  
W. C. Huang

1968 ◽  
Vol 168 (2) ◽  
pp. 337-340 ◽  
Author(s):  
J. Y. Wong

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