Anodic processes. Part VI. The photomicrographic method. Application to the mercury–aqueous hydrochloric acid system

1966 ◽  
Vol 0 (0) ◽  
pp. 111-116 ◽  
Author(s):  
D. C. Cornish ◽  
S. N. Das ◽  
D. J. G. Ives ◽  
R. W. Pittman
Keyword(s):  
Hydrochloric Acid ◽  
Acid System ◽  
Aqueous Hydrochloric Acid

A 35Cl magnetic resonance study of chloride exchange on indium(III) and thallium(III) in aqueous hydrochloric acid solution

1975 ◽  
Vol 28 (9) ◽  
pp. 1901 ◽  
Author(s):  
SF Lincoln ◽  
AC Sandercock ◽  
DR Stranks
Keyword(s):  
Exchange Rate ◽  
Magnetic Resonance ◽  
Hydrochloric Acid ◽  
Acid Solution ◽  
Hydrochloric Acid Solution ◽  
Magnetic Resonance Study ◽  
Aqueous Hydrochloric Acid ◽  
Chloride Exchange ◽  
Lower Limits ◽  
Aqueous Hydrochloric Acid Solution

The parameters describing chloride exchange on indium(III), determined by 35Cl N.M.R., are: k(298 K)= (8.8�0+4) x 106 s-1, ΔH? = 45.7�2.3 kJ mol-1 and ΔS? = 42�8 J mol-1 K-1; and k(298 K)= (2.0�0.1)x106 s-1, ΔH? = 37.7�1.9 kJ mol-1, and ΔS? = 3�6 J mol-1 K-1 in 10.95M and 7.00M aqueous hydrochloric acid respectively, calculated from the observed exchange rate kex4[InCl4(H2O)2-].��� For thallium(III) lower limits of kex(219 K) = 1.6 x 106 s-1 and 1.3 x 106 s-1 were obtained in 10.95M and 7.00M aqueous hydrochloric acid, respectively, where [TlCl6]3- is assumed to be the exchanging species.

scholarly journals Microwave-assisted Depolymerization of Lignin with Metal Chloride in a Hydrochloric Acid and Formic Acid System

BioResources ◽  
2018 ◽  
Vol 13 (2) ◽  
Author(s):  
Rongge Zou ◽  
Yunfeng Zhao ◽  
Yunpu Wang ◽  
Dengle Duan ◽  
Liangliang Fan ◽  
...  
Keyword(s):  
Hydrochloric Acid ◽  
Formic Acid ◽  
Metal Chloride ◽  
Acid System ◽  
Microwave Assisted
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