Determination of the structural configuration and the cross-linking reaction between 2-p-(formylstyryl)-3,4-dimethylthiazol-3-ium moieties in photosensitive polymers

1993 ◽  
Vol 89 (24) ◽  
pp. 4327
Author(s):  
Ian C. Barker ◽  
Norman S. Allen ◽  
Michele Edge ◽  
John A. Sperry ◽  
Richard J. Batten
Keyword(s):  
Cross Linking ◽  
Structural Configuration ◽  
Photosensitive Polymers ◽  
The Cross

Determination of the cross-linking degree of commercial ethylene-vinyl-acetate polymer by luminescence spectroscopy

2014 ◽  
Vol 21 (5) ◽  
Author(s):  
Jan Caspar Schlothauer ◽  
Rojonirina Maryline Ralaiarisoa ◽  
Arnaud Morlier ◽  
Marc Köntges ◽  
Beate Röder
Keyword(s):  
Vinyl Acetate ◽  
Ethylene Vinyl Acetate ◽  
Luminescence Spectroscopy ◽  
Cross Linking ◽  
The Cross

Non-destructive determination of the cross-linking degree of EVA by Raman Spectroscopy

2014 ◽  
Vol 2014 (1) ◽  
pp. 14-21 ◽  
Author(s):  
Cornelia Peike ◽  
◽  
Witchuda Phondongnok ◽  
Thomas Kaltenbach ◽  
Karl-Anders Weiss ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Cross Linking ◽  
The Cross ◽  
Non Destructive

scholarly journals Investigation of the functional network modifier loading on the stoichiometric ratio of epoxy resins and their dielectric properties

2021 ◽  
Author(s):  
Istebreq A. Saeedi ◽  
Sunny Chaudhary ◽  
Thomas Andritsch ◽  
Alun S. Vaughan
Keyword(s):  
Glass Transition ◽  
Dielectric Properties ◽  
Electrical Properties ◽  
Epoxy Resins ◽  
Functional Network ◽  
Cross Linking ◽  
Network Modifier ◽  
Epoxy Resin System ◽  
The Cross ◽  
The Impact

AbstractReactive molecular additives have often been employed to tailor the mechanical properties of epoxy resins. In addition, several studies have reported improved electrical properties in such systems, where the network architecture and included function groups have been modified through the use of so-called functional network modifier (FNM) molecules. The study reported here set out to investigate the effect of a glycidyl polyhedral oligomeric silsesquioxane (GPOSS) FNM on the cross-linking reactions, glass transition, breakdown strength and dielectric properties of an amine-cured epoxy resin system. Since many previous studies have considered POSS to act as an inorganic filler, a key aim was to consider the impact of GPOSS addition on the stoichiometry of curing. Fourier transform infrared spectroscopy revealed significant changes in the cross-linking reactions that occur if appropriate stoichiometric compensation is not made for the additional epoxide groups present on the GPOSS. These changes, in concert with the direct effect of the GPOSS itself, influence the glass transition temperature, dielectric breakdown behaviour and dielectric response of the system. Specifically, the work shows that the inclusion of GPOSS can result in beneficial changes in electrical properties, but that these gains are easily lost if consequential changes in the matrix polymer are not appropriately counteracted. Nevertheless, if the system is appropriately optimized, materials with pronounced improvements in technologically important characteristics can be designed.

scholarly journals Alignment determination of the Hayabusa2 laser altimeter (LIDAR)

2021 ◽  
Vol 73 (1) ◽  
Author(s):  
Hirotomo Noda ◽  
Hiroki Senshu ◽  
Koji Matsumoto ◽  
Noriyuki Namiki ◽  
Takahide Mizuno ◽  
...  
Keyword(s):  
Altimeter Data ◽  
Gravity Assist ◽  
Laser Altimeter ◽  
Trajectory Error ◽  
Flight Data ◽  
Camera Image ◽  
Operation Period ◽  
The Cross ◽  
Along Track

AbstractIn this study, we determined the alignment of the laser altimeter aboard Hayabusa2 with respect to the spacecraft using in-flight data. Since the laser altimeter data were used to estimate the trajectory of the Hayabusa2 spacecraft, the pointing direction of the altimeter needed to be accurately determined. The boresight direction of the receiving telescope was estimated by comparing elevations of the laser altimeter data and camera images, and was confirmed by identifying prominent terrains of other datasets. The estimated boresight direction obtained by the laser link experiment in the winter of 2015, during the Earth’s gravity assist operation period, differed from the direction estimated in this study, which fell on another part of the candidate direction; this was not selected in a previous study. Assuming that the uncertainty of alignment determination of the laser altimeter boresight was 4.6 pixels in the camera image, the trajectory error of the spacecraft in the cross- and/or along-track directions was determined to be 0.4, 2.1, or 8.6 m for altitudes of 1, 5, or 20 km, respectively.

scholarly journals The Effect of Surfactant-Modified Montmorillonite on the Cross-Linking Efficiency of Polysiloxanes

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2623
Author(s):  
Monika Wójcik-Bania ◽  
Jakub Matusik
Keyword(s):  
Total Pore Volume ◽  
Cross Linking ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
The Cross ◽  
Chain Lengths ◽  
First Time ◽  
Substituent Influence ◽  
Benzyl Substituent

Polymer–clay mineral composites are an important class of materials with various applications in the industry. Despite interesting properties of polysiloxanes, such matrices were rarely used in combination with clay minerals. Thus, for the first time, a systematic study was designed to investigate the cross-linking efficiency of polysiloxane networks in the presence of 2 wt % of organo-montmorillonite. Montmorillonite (Mt) was intercalated with six quaternary ammonium salts of the cation structure [(CH3)2R’NR]+, where R = C12, C14, C16, and R’ = methyl or benzyl substituent. The intercalation efficiency was examined by X-ray diffraction, CHN elemental analysis, and Fourier transform infrared (FTIR) spectroscopy. Textural studies have shown that the application of freezing in liquid nitrogen and freeze-drying after the intercalation increases the specific surface area and the total pore volume of organo-Mt. The polymer matrix was a poly(methylhydrosiloxane) cross-linked with two linear vinylsiloxanes of different siloxane chain lengths between end functional groups. X-ray diffraction and transmission electron microscopy studies have shown that the increase in d-spacing of organo-Mt and the benzyl substituent influence the degree of nanofillers’ exfoliation in the nanocomposites. The increase in the degree of organo-Mt exfoliation reduces the efficiency of hydrosilylation reaction monitored by FTIR. This was due to physical hindrance induced by exfoliated Mt particles.

Effects of a crosslinking agent on a supramolecular gel to control lost circulation

2021 ◽  
Vol 45 (16) ◽  
pp. 7089-7095
Author(s):  
Bo Wang ◽  
Jinsheng Sun ◽  
Kaihe Lv ◽  
Feng Shen ◽  
Yingrui Bai
Keyword(s):  
Crosslinking Agent ◽  
Network Density ◽  
Cross Linking ◽  
Supramolecular Gel ◽  
Lost Circulation ◽  
The Cross

The Cr3+ can improve the cross-linking degree and network density of the GP-A gel, and enhance its strength and plugging ability to control lost circulation.

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