Optical–optical double resonance studies of the halogen ion-pair states. Part 3.—The F(0+u)→ X(0+g) transition dipole moment function in I2

1992 ◽  
Vol 88 (12) ◽  
pp. 1599-1603 ◽  
Author(s):  
Philip J. Jewsbury ◽  
Kenneth P. Lawley ◽  
Trevor Ridley ◽  
Robert J. Donovan
Keyword(s):  
Dipole Moment ◽  
Double Resonance ◽  
Transition Dipole Moment ◽  
Ion Pair ◽  
Moment Function ◽  
Transition Dipole ◽  
Optical Double Resonance

Electronic transition dipole moment and radiative lifetime calculations of lithium dimer ion-pair states

2019 ◽  
Vol 355 ◽  
pp. 1-7 ◽  
Author(s):  
Aydin Sanli ◽  
Xinhua Pan ◽  
David S. Beecher ◽  
Sylvie Magnier ◽  
A. Marjatta Lyyra ◽  
...  
Keyword(s):  
Dipole Moment ◽  
Electronic Transition ◽  
Radiative Lifetime ◽  
Transition Dipole Moment ◽  
Ion Pair ◽  
Transition Dipole ◽  
Lithium Dimer

The transition dipole moment function of the chlorine E0g+(3P2)−B3Π0u+ system

1998 ◽  
Vol 109 (24) ◽  
pp. 10864-10872 ◽  
Author(s):  
N. K. Bibinov ◽  
V. K. Davydov ◽  
A. A. Fateev ◽  
D. B. Kokh ◽  
E. V. Lugovoj ◽  
...  
Keyword(s):  
Dipole Moment ◽  
Transition Dipole Moment ◽  
Moment Function ◽  
Transition Dipole

Electronic transition dipole moment and radiative lifetime calculations of sodium dimer ion-pair states

2015 ◽  
Vol 143 (10) ◽  
pp. 104304 ◽  
Author(s):  
Aydin Sanli ◽  
Bediha Beser ◽  
John R. Edwardson ◽  
Sylvie Magnier ◽  
Ergin H. Ahmed ◽  
...  
Keyword(s):  
Dipole Moment ◽  
Electronic Transition ◽  
Radiative Lifetime ◽  
Transition Dipole Moment ◽  
Ion Pair ◽  
Transition Dipole ◽  
Sodium Dimer

Theoretical studies on the one- and two-photon absorption of tetrabenzoporphyrins and phthalocyanines

2004 ◽  
Vol 82 (1) ◽  
pp. 19-26 ◽  
Author(s):  
Xin Zhou ◽  
Ai-Min Ren ◽  
Ji-Kang Feng ◽  
Xiao-Juan Liu
Keyword(s):  
Dipole Moment ◽  
Cross Sections ◽  
Density Functional ◽  
Transition Dipole Moment ◽  
Photon Absorption ◽  
Transition Dipole ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Order Of Magnitude ◽  
The One

The one-photon absorption (OPA) properties of tetrabenzoporphyrins (TBPs) and phthalocyanines (Pcs) were studied using the semiempirical ZINDO method and time-dependent density functional theory (TDDFT), respectively. The compared results confirmed that the semiempirical ZINDO method was reasonably reliable when calculating the OPA of tetrabenzoporphyrins and phthalocyanines. On the basis of the OPA properties obtained from the ZINDO method, two-photon absorption (TPA) properties of two series of molecules were investigated, using ZINDO and sum-over-states (SOS) methods. The results showed that the TPA cross-sections of all molecules were in the range of 220.6 × 10–50 – 345.9 × 10–50 cm4·s·photon–1, which were in the same order of magnitude as the values reported in the literature. The relatively larger δ(ω) value for Pcs with respect to that for corresponding TBPs originates from larger intramolecular charge transfer, which can be characterized by the difference of dipole moment between S0 and S1 and the transition dipole moment between S1 and S5.Key words: two-photon absorption, ZINDO, sum-over-states, tetrabenzoporphyrin, phthalocyanines.

Sign in / Sign up

Export Citation Format

Share Document