Electrical conductances for some tetraalkylammonium bromides, lithium tetrafluoroborate and tetrabutylammonium tetrabutylborate in propylene carbonate at 25 °C

1991 ◽  
Vol 87 (21) ◽  
pp. 3511-3513 ◽  
Author(s):  
Prakash K. Muhuri ◽  
Dilip K. Hazra
Keyword(s):  
Propylene Carbonate ◽  
Tetraalkylammonium Bromides ◽  
Electrical Conductances ◽  
Lithium Tetrafluoroborate

scholarly journals Viscosity B Coefficients of Some Tetraalkylammonium Bromides, Lithium Tetrafluoroborate and Tetrabutylammonium Tetraphenyl borate in Propylene Carbonate

1993 ◽  
Vol 48 (3) ◽  
pp. 523-528 ◽  
Author(s):  
Prakash K. Muhuri ◽  
Dilip K. Hazra
Keyword(s):  
Transition State ◽  
Thermodynamic Parameters ◽  
Propylene Carbonate ◽  
Measured Temperature ◽  
B Values ◽  
Tetraalkylammonium Bromides ◽  
Einstein's Equation ◽  
Lithium Tetrafluoroborate ◽  
Tetraphenyl Borate ◽  
B Coefficients

Abstract The viscosities of solutions of tetraalkylammonium bromides, R4NBr (R = -C2H5 to -C7H15), lithium tetrafluoroborate (LiBF4) and tetrabutylammonium tetraphenylborate (Bu4NBPh4) in propylene carbonate (PC) have been measured at 25, 35 and 45 °C. The relative viscosities have been analyzed using the Jones-Dole equation in the form of unassociated electrolytes, and the viscosity B-coefficients have been evaluated. The thermodynamic parameters have been calculated using the transition-state treatment and the measured temperature dependencies. Ionic B values have also been derived and discussed in terms of Einstein's equation. The analysis shows that Li+ is highly solvated compared to other cations and anions in this medium.

Optical and Electrical Properties of Organic Conducting Polymers

2014 ◽  
Vol 8 (1) ◽  
pp. 1457-1463
Author(s):  
Salah Abdulla Hasoon
Keyword(s):  
Electrical Properties ◽  
Conjugated Polymer ◽  
Polymeric Materials ◽  
Quantum Mechanical ◽  
Optical And Electrical Properties ◽  
Electrically Conducting ◽  
Temperature Ranges ◽  
Lithium Tetrafluoroborate ◽  
Absorbance Peak ◽  
Polymerization Method

Novel electrically conducting polymeric materials are prepared in this work. Polythiophene (PT) and poly (3-Methelthiophene) (P3MT) films were prepared by electro-polymerization method using cyclic voltammetry in acetonitrile as a solvent and lithium tetrafluoroborate as the electrolyte on a gold electrode. Electrical properties of P3MT have been examined in different environments using UV-Vis absorption spectroscopy and quantum mechanical ab initio calculations, The observed absorption peaks at 314 and 415 nm, were attributed to the n-π* and π-π* transitions, respectively in the conjugated polymer chain, in contrast, the observed absorbance peak at 649 nm, is responsible for electric conduction. The temperature dependence of the conductivity can be fitted to the Arrhenius and the VTF equations in different temperature ranges.

Acyclic Acetals in Propylene Carbonate-Based Electrolytes for Advanced and Safer Graphite-Based Lithium Ion Batteries

2020 ◽  
Vol 167 (4) ◽  
pp. 040509 ◽  
Author(s):  
J. Atik ◽  
S. Röser ◽  
R. Wagner ◽  
D. Berghus ◽  
M. Winter ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Propylene Carbonate ◽  
Lithium Ion

scholarly journals High-Mass Loading Hierarchically Porous Activated Carbon Electrode for Pouch-Type Supercapacitors with Propylene Carbonate-Based Electrolyte

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 785
Author(s):  
Tai-Feng Hung ◽  
Tzu-Hsien Hsieh ◽  
Feng-Shun Tseng ◽  
Lu-Yu Wang ◽  
Chang-Chung Yang ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Propylene Carbonate ◽  
Rational Design ◽  
Rate Capability ◽  
High Mass ◽  
Electrochemical Performances ◽  
Mass Loading ◽  
Hierarchically Porous ◽  
Symmetric Supercapacitor ◽  
Porous Activated Carbon

Rational design and development of the electrodes with high-mass loading yet maintaining the excellent electrochemical properties are significant for a variety of electrochemical energy storage applications. In comparison with the slurry-casted electrode, herein, a hierarchically porous activated carbon (HPAC) electrode with higher mass loading (8.3 ± 0.2 mg/cm2) is successfully prepared. The pouch-type symmetric device (1 cell) with the propylene carbonate-based electrolyte shows the rate capability (7.1 F at 1 mA/cm2 and 4.8 F at 10 mA/cm2) and the cycling stability (83% at 12,000 cycles). On the other hand, an initial discharge capacitance of 32.4 F and the capacitance retention of 96% after 30,000 cycles are delivered from a pouch-type symmetric supercapacitor (five cells). The corresponding electrochemical performances are attributed to the fascinating properties of the HPAC and the synergistic features of the resulting electrode.

Chiral salenCo(iii) complexes with bulky substituents as catalysts for stereoselective alternating copolymerization of racemic propylene oxide with carbon dioxide and succinic anhydride

2021 ◽  
Vol 12 (12) ◽  
pp. 1776-1786
Author(s):  
Zhou Wang ◽  
Ying Mu
Keyword(s):  
Carbon Dioxide ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
Succinic Anhydride ◽  
Poly Propylene ◽  
Alternating Copolymerization

Stereoregular poly(propylene carbonate)s and poly(propylene succinate-block-carbonate)s were synthesized with new chiral salenCo(iii) catalysts carrying bulky substituents.

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