The gas-phase reaction of CF3radicals with HCN in the temperature range 333–523 K

Author(s):  
Silvia Lane ◽  
Elena V. Oexler ◽  
Eduardo H. Staricco
2015 ◽  
Vol 119 (45) ◽  
pp. 11076-11083 ◽  
Author(s):  
Yuri Bedjanian ◽  
Julien Morin ◽  
Manolis N. Romanias

1971 ◽  
Vol 49 (5) ◽  
pp. 803-806 ◽  
Author(s):  
Nick Demchuk ◽  
H. D. Gesser

The gas phase reaction of hydrogen atoms with carbon suboxide was studied over the temperature range of−96 to 235 °C and was found to proceed via a chain reaction. The products found were CH4, CO, CH2CO, C2H6, (CHO)2, and polymer. A mechanism is proposed and the chain reaction is explained by the intermediate formation of ketene and the formyl radical.


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