Pulsed-laser flash and continuous photolysis of ion-pair complexes of methyl viologen and ethylenediamine tetra-acetic acid in aqueous solution

Author(s):  
Dasari R. Prasad ◽  
Morton Z. Hoffman
1986 ◽  
Vol 108 (17) ◽  
pp. 5135-5142 ◽  
Author(s):  
Dasari R. Prasad ◽  
Morton Z. Hoffman ◽  
Quinto G. Mulazzani ◽  
Michael A. J. Rodgers

Author(s):  
S. V. A. R. SASTRY ◽  
SRI ADIBATLA ANUSHA ◽  
S. VARUN ◽  
◽  
◽  
...  

1998 ◽  
Vol 72 (7) ◽  
pp. 789-791 ◽  
Author(s):  
Hideaki Kurita ◽  
Akinori Takami ◽  
Seiichiro Koda

1992 ◽  
Vol 57 (1) ◽  
pp. 26-32 ◽  
Author(s):  
N. M. Guindy ◽  
F. M. Elzawawy ◽  
D. Y. Sabry

The photochemistry of free-base meso-tetraphenylporphyrin linked to methyl viologen via an alkoxy chain (n = 3) at the ortho, meta or para-position of one meso-phenyl group, in Triton X-100 micellar aqueous solutions is reported. The appended viologen does not quench the porphyrin fluorescence nor its triplet excited state due to the different solubilization of both parts of the molecule in the medium where the porphyrin ring resides in the hydrophobic phase and the alkoxy linker protrudes into the rather diffuse outer phase of detergent oxyethylene units, while the viologen moiety penetrates into the aqueous layer. However, laser flash photolysis measurements show that in the presence of nicotinamide dinucleotide, NADH, the porphyrin ring is reduced to phlorin due to the penetration of NADH into the organic phase. For porphyrin-tetraviologen in which a viologen molecule is linked to each of the porphyrin meso-position via alkoxy chain, fluorescence quenching could be achieved. The values of the quenching efficiency are high (94% in acetonitrile) compared to intramolecular quenching and are dependent upon the solvent viscosity.


PEDIATRICS ◽  
1980 ◽  
Vol 66 (1) ◽  
pp. 132-134
Author(s):  
James Seidel

Polyvinyl alcohol preservative (PVA) is used routinely in the laboratory for collection of specimens for examination for ova and parasites.1-4 PVA, presently used at Harbor-UCLA Medical Center, contains: 4.5% mercuric chloride, 5% polyvinyl alcohol, 30% denatured alcohol, 4.5% acetic acid, and 1.5% glycerin in an aqueous solution. The kit, as shown in the Figure, contains three bottles with 10-ml aliquots of PVA, wooden sticks for mixing the specimen, and written instructions for collection of the specimens. The bottles are clearly labeled as poison in English and Spanish, and specific verbal as well as written instructions are given to patients and their families when the ova and parasite kits are dispensed.


Molecules ◽  
2017 ◽  
Vol 22 (5) ◽  
pp. 816 ◽  
Author(s):  
Matteo Savastano ◽  
Carla Bazzicalupi ◽  
Claudia Giorgi ◽  
Paola Gratteri ◽  
Antonio Bianchi

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