Structure of the σ* radical anion in irradiated iodoacetamide. An electron paramagnetic resonance and INDO study

1984 ◽  
Vol 80 (3) ◽  
pp. 267-274 ◽  
Author(s):  
Per-Olof Samskog ◽  
Lowell D. Kispert ◽  
Balaraman Kalyanaraman
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Radical Anion ◽  
Paramagnetic Resonance ◽  
Electron Paramagnetic

Electron paramagnetic resonance and INDO study of carbon-13 hyperfine splitting constants in benzyl radical and toluene radical anion

1975 ◽  
Vol 97 (16) ◽  
pp. 4477-4482 ◽  
Author(s):  
Arthur M. Ihrig ◽  
Paul Ronald Jones ◽  
Il Nam Jung ◽  
Roger V. Lloyd ◽  
James L. Marshall ◽  
...  
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Hyperfine Splitting ◽  
Radical Anion ◽  
Paramagnetic Resonance ◽  
Benzyl Radical ◽  
Electron Paramagnetic

Evidence for the interaction between tBuOK and 1,10-phenanthroline to form the 1,10-phenanthroline radical anion: a key step for the activation of aryl bromides by electron transfer

2015 ◽  
Vol 51 (3) ◽  
pp. 545-548 ◽  
Author(s):  
Hong Yi ◽  
Anny Jutand ◽  
Aiwen Lei
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Electron Transfer ◽  
Radical Anion ◽  
Outer Sphere ◽  
Aryl Bromide ◽  
Aryl Radical ◽  
Paramagnetic Resonance ◽  
Aryl Bromides ◽  
Outer Sphere Electron Transfer ◽  
Electron Paramagnetic

Electron paramagnetic resonance and electrochemistry are utilized to the interaction between 1,10-phenanthroline (Phen) and KOtBu to form the radical anion Phen˙−via an inner-sphere electron transfer. An aryl radical is then formed from aryl bromide via outer-sphere electron transfer from Phen˙−.

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