Determination of molecular structure parameters on the basis of gas-adsorption chromatography data. Part 2.—Determination of potential barriers and equilibrium angles of internal rotation for methyl derivatives of biphenyl and for terphenyls

Author(s):  
Arunas J. Grumadas ◽  
Dionizas P. Poshkus ◽  
Andrei V. Kiselev
2019 ◽  
Vol 109 ◽  
pp. 00101
Author(s):  
Oleksandr Topal ◽  
Iryna Holenko ◽  
Inna Diakun

The results of determination of parameters of porous structure of coal and char particles are presented. They were determined using gas adsorption method and thermal decomposition of particles in air oxygen. The porous structure parameters allow predicting char reactivity change at different temperatures as well as during conversion in accordance with Random Pore Model (RPM-model).


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