Relaxation processes in some intramolecularly hydrogen-bonded compounds

1981 ◽  
Vol 77 (7) ◽  
pp. 1143 ◽  
Author(s):  
Muhammad A. Mazid ◽  
Muhammad A. Enayetullah ◽  
Stanley Walker
Keyword(s):  
Relaxation Processes ◽  
Hydrogen Bonded

scholarly journals A microscopic look at the Johari-Goldstein relaxation in a hydrogen-bonded glass-former

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
F. Caporaletti ◽  
S. Capaccioli ◽  
S. Valenti ◽  
M. Mikolasek ◽  
A. I. Chumakov ◽  
...  
Keyword(s):  
Time Domain ◽  
Glassy State ◽  
Center Of Mass ◽  
Relaxation Processes ◽  
Undercooled Liquid ◽  
Microscopic Scale ◽  
Glass Forming ◽  
Full Explanation ◽  
Molecular Scale ◽  
Hydrogen Bonded

Abstract Understanding the glass transition requires getting the picture of the dynamical processes that intervene in it. Glass-forming liquids show a characteristic decoupling of relaxation processes when they are cooled down towards the glassy state. The faster (βJG) process is still under scrutiny, and its full explanation necessitates information at the microscopic scale. To this aim, nuclear γ-resonance time-domain interferometry (TDI) has been utilized to investigate 5-methyl-2-hexanol, a hydrogen-bonded liquid with a pronounced βJG process as measured by dielectric spectroscopy. TDI probes in fact the center-of-mass, molecular dynamics at scattering-vectors corresponding to both inter- and intra-molecular distances. Our measurements demonstrate that, in the undercooled liquid phase, the βJG relaxation can be visualized as a spatially-restricted rearrangement of molecules within the cage of their closest neighbours accompanied by larger excursions which reach out at least the inter-molecular scale and are related to cage-breaking events. In-cage rattling and cage-breaking processes therefore coexist in the βJG relaxation.

An Unnatural Amino Acid that Mimics a Tripeptide β-Strand and Forms β-Sheetlike Hydrogen-Bonded Dimers [J. Am. Chem. Soc.2000,122, 7654-7661]. 

2001 ◽  
Vol 123 (7) ◽  
pp. 1545-1546
Author(s):  
James S. Nowick ◽  
De Michael Chung ◽  
Kalyani Maitra ◽  
Santanu Maitra ◽  
Kimberly D. Stigers ◽  
...  
Keyword(s):  
Amino Acid ◽  
Unnatural Amino Acid ◽  
Hydrogen Bonded

Hydrogen-Bonded Solvent Systems

1969 ◽  
Vol 67 (1_3) ◽  
pp. 168-168
Author(s):  
H. G. Hertz
Keyword(s):  
Solvent Systems ◽  
Hydrogen Bonded

Energy Dissipation Processes of Singlet Excited 1-Hydroxyfluorenone and its Hydrogen-Bonded Complex with N-Methylimidazole

2004 ◽  
Author(s):  
Krisztina Sebők-Nagy ◽  
László Biczók ◽  
Akimitsu Morimoto ◽  
Tetsuya Shimada ◽  
Haruo Inoue
Keyword(s):  
Energy Dissipation ◽  
Dissipation Processes ◽  
Hydrogen Bonded
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