Solubilities of salts and kinetics of reactions involving inorganic complex ions in aqueous acetone mixtures. Derivation of transfer chemical potentials for ions in these aqueous mixtures at ambient pressure and 298.2 K

1988 ◽  
Vol 84 (4) ◽  
pp. 1243 ◽  
Author(s):  
Michael J. Blandamer ◽  
Barbara Briggs ◽  
John Burgess ◽  
Pilar Guardado ◽  
Stojan Radulovic ◽  
...  
Keyword(s):  
Ambient Pressure ◽  
Aqueous Acetone ◽  
Aqueous Mixtures ◽  
Complex Ions ◽  
Inorganic Complex ◽  
Chemical Potentials ◽  
Kinetics Of

Modeling of sorption kinetics of U(VI) micro-quantities nanostructured materials with anatase mesoporous structures

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Veniamin Zheleznov ◽  
Aleksey Golikov ◽  
Tatiana Sokolnitskaya ◽  
Sergey Ivannikov
Keyword(s):  
Nanostructured Materials ◽  
Sorption Kinetics ◽  
Uranyl Ion ◽  
Competitive Sorption ◽  
Hydroxyl Groups ◽  
Complex Ions ◽  
The Stability ◽  
Kinetics Of ◽  
Mesoporous Structures ◽  
Ionic Forms

Abstract The sorption kinetics of uranyl ions micro-quantities from fluoride solutions by nanostructured materials with anatase mesoporous structures has been studied. Using the model of competitive sorption of ions and positively charged complexes of uranyl ion on deprotonated hydroxyl groups of an anatase, kinetic curves of changes in the ratio of ionic forms of uranium in solution were calculated. Modeling was carried out under the assumption of a two-stage mechanism of uranium complex ions sorption. The modeling considered the influence of the uranyl ion carbonate complexes formation. The shift in equilibrium among ionic forms of uranyl correlates with the stability of the complexes in solution.

Freeze Drying Kinetics of Sucrose-NaCl-Protein Aqueous Mixtures

1998 ◽  
Vol 51 (3) ◽  
pp. 905-911 ◽  
Author(s):  
J. M. Saiter ◽  
N. Delahaye ◽  
A. Bardat ◽  
E. Chatenet
Keyword(s):  
Freeze Drying ◽  
Drying Kinetics ◽  
Aqueous Mixtures ◽  
Kinetics Of

Chelating agents in high temperature aqueous chemistry. 1. The kinetics of the thermal decomposition of aqueous nitrilotriacetate (NTA), iminodiacetate (IDA), and N-methyliminodiacetate (MIDA)

1977 ◽  
Vol 55 (10) ◽  
pp. 1762-1769 ◽  
Author(s):  
Meindert Booy ◽  
Thomas Wilson Swaddle
Keyword(s):  
Chelating Agents ◽  
Nuclear Reactors ◽  
Rate Coefficients ◽  
Aqueous Mixtures ◽  
Hydrothermal Conditions ◽  
Good Thermal Stability ◽  
First Order ◽  
First Order Kinetics ◽  
Kinetics Of ◽  
Thermal Stability Of

Aqueous H3NTA, H2MIDA, H2IDA, and their anions decompose under hydrothermal conditions (400–580 K) according to first order kinetics by successive decarboxylations, oxidation by O2 being unimportant except at the highest temperatures. In the presence of added H+, the species H4NTA+ and, to a lesser extent, H3MIDA+ (but not H3IDA+), provide significant decomposition pathways through elimination of a —CH2COO— group (deacetylation). For HnNTA(3−n)−, first order rate coefficients kn for decomposition are k0 = 4.5 × 10−7, k1 ∼ 1 × 10−6, k2 ∼ 7 × 10−5, k3 = 2.1 × 10−4, and k4 = 1.0 × 10−2 s1, at 503 K and ionic strength 2.0 m, the spread in rates being due to differences in ΔS* rather than ΔH*. H2MIDA and H2IDA are comparable in reactivity to H3NTA, while their anions are much less reactive than the NTA species of the same charge. The good thermal stability of aqueous NTA commends it as a reagent for boiler servicing and for decontamination of water-cooled nuclear reactors. A potentiometric method for the estimation of mono-, di-, and tribasic aminoacids in aqueous mixtures of these is described.

Fast Gas-Solid Reaction Kinetics of Nanoparticles Unveiled by Millisecond In Situ Electron Diffraction at Ambient Pressure

2018 ◽  
Vol 57 (35) ◽  
pp. 11344-11348 ◽  
Author(s):  
Jian Yu ◽  
Wentao Yuan ◽  
Hangsheng Yang ◽  
Qiang Xu ◽  
Yong Wang ◽  
...  
Keyword(s):  
Electron Diffraction ◽  
Reaction Kinetics ◽  
Ambient Pressure ◽  
Solid Reaction ◽  
Kinetics Of ◽  
Gas Solid Reaction
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