scholarly journals Interaction between zeolites and cluster compounds. Part 1.—Adsorption of iron pentacarbonyl on zeolites

1983 ◽  
Vol 79 (8) ◽  
pp. 1819 ◽  
Author(s):  
Thomas Bein ◽  
Peter A. Jacobs
Keyword(s):  
Iron Pentacarbonyl ◽  
Cluster Compounds

Alkylation of Cymantrene with 1-Bromoadamantane Initiated by Iron Pentacarbonyl

INEOS OPEN ◽  
2019 ◽  
Vol 2 (1) ◽  
Author(s):  
Т. Т. Vasil'eva ◽  
◽  
H. H. Hambardzumyan ◽  
N. Е. Mysova ◽  
O. N. Gorunova ◽  
...  
Keyword(s):  
Iron Pentacarbonyl

Semibridging Phenyl Ligands in Iridium–Copper and Iridium–Silver Cluster Compounds: Synthesis, Structures, and Bonding

2013 ◽  
Vol 32 (8) ◽  
pp. 2416-2426 ◽  
Author(s):  
Richard D. Adams ◽  
Mingwei Chen ◽  
Gaya Elpitiya ◽  
Xinzheng Yang ◽  
Qiang Zhang
Keyword(s):  
Silver Cluster ◽  
Cluster Compounds

scholarly journals Facile Organometallic Synthesis of Fe-Based Nanomaterials by Hot Injection Reaction

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1141
Author(s):  
Georgia Basina ◽  
Hafsa Khurshid ◽  
Nikolaos Tzitzios ◽  
George Hadjipanayis ◽  
Vasileios Tzitzios
Keyword(s):  
Room Temperature ◽  
Colloidal Particles ◽  
Iron Pentacarbonyl ◽  
Vibrating Sample Magnetometer ◽  
X Ray Diffraction ◽  
Organometallic Synthesis ◽  
X Ray ◽  
Transmission Electron ◽  
Hot Injection ◽  
The Stability

Fe-based colloids with a core/shell structure consisting of metallic iron and iron oxide were synthesized by a facile hot injection reaction of iron pentacarbonyl in a multi-surfactant mixture. The size of the colloidal particles was affected by the reaction temperature and the results demonstrated that their stability against complete oxidation related to their size. The crystal structure and the morphology were identified by powder X-ray diffraction and transmission electron microscopy, while the magnetic properties were studied at room temperature with a vibrating sample magnetometer. The injection temperature plays a very crucial role and higher temperatures enhance the stability and the resistance against oxidation. For the case of injection at 315 °C, the nanoparticles had around a 10 nm mean diameter and revealed 132 emu/g. Remarkably, a stable dispersion was created due to the colloids’ surface functionalization in a nonpolar solvent.

On the reaction of GeCl2·dioxane with KFeCp(CO)2: isolation and characterization of novel bimetallic clusters

2019 ◽  
Vol 48 (12) ◽  
pp. 3831-3834 ◽  
Author(s):  
Lars Preißing ◽  
Claudio Schrenk ◽  
Andreas Schnepf
Keyword(s):  
Cluster Compounds ◽  
Bimetallic Clusters ◽  
Complex Reaction ◽  
Reaction Route ◽  
Isolation And Characterization

The reaction of GeCl2·dioxane with KFeCp(CO)2 leads to polyhedral cluster compounds with six germanium atoms like Ge6[FeCp(CO)2]6 or Ge6Cl2[FeCp(CO)2]6via a complex reaction route.

scholarly journals Synthesis, Crystal Structure, and Luminescence of Metal Iodide Cluster Compounds ( n Bu 4 N) 2 [ M 6 I 8 (NCO) 6 ] with M = Mo, W

2020 ◽  
Vol 646 (19) ◽  
pp. 1650-1654
Author(s):  
Arin‐Daniel Fuhrmann ◽  
Florian Pachel ◽  
Markus Ströbele ◽  
David Enseling ◽  
Thomas Jüstel ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Cluster Compounds ◽  
Metal Iodide
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