Structure of aqueous electrolyte solutions. Ionic internal pressures and proton chemical shifts

1983 ◽  
Vol 79 (5) ◽  
pp. 1123 ◽  
Author(s):  
Jean V. Leyendekkers
Keyword(s):  
Aqueous Electrolyte ◽  
Chemical Shifts ◽  
Electrolyte Solutions ◽  
Aqueous Electrolyte Solutions ◽  
Internal Pressures ◽  
Proton Chemical Shifts

The Investigation of Cation–Anion Interactions by 39K Nuclear Magnetic Resonance

1972 ◽  
Vol 50 (23) ◽  
pp. 3926-3930 ◽  
Author(s):  
E. G. Bloor ◽  
R. G. Kidd
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Aqueous Electrolyte ◽  
Chemical Shifts ◽  
Electrolyte Solutions ◽  
Outer Electron ◽  
Aqueous Electrolyte Solutions ◽  
Nuclear Magnetic

The 39K chemical shifts in a number of aqueous electrolyte solutions have been determined. These arise from the overlapping of the outer electron orbitals of the anion and cation during random ionic collisions. The magnitudes of the chemical shifts are shown to be directly proportional to the effectiveness of this overlap interaction.

Promoting Nitrogen Electroreduction to Ammonia with Bismuth Nanocrystals and Potassium Cations in Water

2020 ◽  
Author(s):  
Jaecheol Choi ◽  
Hoang-Long Du ◽  
Manjunath Chatti ◽  
Bryan H. R. Suryanto ◽  
Alexandr Simonov ◽  
...  
Keyword(s):  
Electrocatalytic Activity ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Reduction Reaction ◽  
Nitrogen Reduction ◽  
Aqueous Electrolyte Solutions

We demonstrate that bismuth exhibits no measurable electrocatalytic activity for the nitrogen reduction reaction to ammonia in aqueous electrolyte solutions, contrary to several recent reports on the highly impressive rates of Bi-catalysed electrosynthesis of NH<sub>3</sub> from N<sub>2</sub>.

scholarly journals Macroscopic conductivity of aqueous electrolyte solutions scales with ultrafast microscopic ion motions

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Vasileios Balos ◽  
Sho Imoto ◽  
Roland R. Netz ◽  
Mischa Bonn ◽  
Douwe Jan Bonthuis ◽  
...  
Keyword(s):  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Aqueous Electrolyte Solutions

NMR Studies of Aqueous Electrolyte Solutions. IV. Hydration Numbers of Strong Electrolytes Determined from Temperature Effects on Proton Shifts

1971 ◽  
Vol 54 (1) ◽  
pp. 178-181 ◽  
Author(s):  
Brother Ferdinand J. Vogrin ◽  
Paul S. Knapp ◽  
William L. Flint ◽  
Arthur Anton ◽  
Gerald Highberger ◽  
...  
Keyword(s):  
Temperature Effects ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Hydration Numbers ◽  
Nmr Studies ◽  
Aqueous Electrolyte Solutions ◽  
Strong Electrolytes
Sign in / Sign up

Export Citation Format

Share Document