Titanium dioxide–electrolyte interface. Part 1.—Gas adsorption and tritium exchange studies

Author(s):  
David E. Yates ◽  
Robert O. James ◽  
Thomas W. Healy
1994 ◽  
Vol 376 ◽  
Author(s):  
Zhu Zhu ◽  
Min Lin ◽  
Geula Dagan ◽  
Micha Tomkiewicz

ABSTRACTThe microstructral characteristics of titanium dioxide aerogels were studied by Small Angle Neutron Scattering (SANS). A variety of models were used to extract the morphological parameters from the SANS data. The evaluation of scattering data was found to be consistent with nitrogen gas adsorption and TEM measurements of a model of aerogel consisting of a light density matrix in which meso- and macro-pores are embedded.


2011 ◽  
Vol 13 (12) ◽  
pp. 7029-7039 ◽  
Author(s):  
Ryan F. LeBouf ◽  
Bon Ki Ku ◽  
Bean T. Chen ◽  
David G. Frazer ◽  
Jared L. Cumpston ◽  
...  

2015 ◽  
Vol 670 ◽  
pp. 3-8 ◽  
Author(s):  
Valentina V. Smirnova ◽  
Alexander P. Ilyin ◽  
Anton S. Brichkov ◽  
Anastasiya V. Zabolotskaya

This article deals with the study of direct current (DC), ultrasonic, and of electrolyte of the influence on the change of titanium dioxide sorption properties. The TiO2 prepared by the TiCl4 hydrolysis method. Attention is drawn to charging exchange processes the surface of titanium dioxide particles after they pass through a layer of counter ions in an aqueous medium under the influence of a DC. The stages of the end product’s formation using methods of the X-ray diffraction, the differential thermal and the infrared spectrometric and the gas adsorption analysis were proposed. Dependence of redistribution sorption active centers at the surface of TiO2 was proved.


Author(s):  
A. Legrouri

The industrial importance of metal catalysts supported on reducible oxides has stimulated considerable interest during the last few years. This presentation reports on the study of the physicochemical properties of metallic rhodium supported on vanadium pentoxide (Rh/V2O5). Electron optical methods, in conjunction with other techniques, were used to characterise the catalyst before its use in the hydrogenolysis of butane; a reaction for which Rh metal is known to be among the most active catalysts.V2O5 powder was prepared by thermal decomposition of high purity ammonium metavanadate in air at 400 °C for 2 hours. Previous studies of the microstructure of this compound, by HREM, SEM and gas adsorption, showed it to be non— porous with a very low surface area of 6m2/g3. The metal loading of the catalyst used was lwt%Rh on V2Q5. It was prepared by wet impregnating the support with an aqueous solution of RhCI3.3H2O.


2009 ◽  
Vol 00 (00) ◽  
pp. 090915102728058-8
Author(s):  
Yoshiteru Kato ◽  
Yasuhiko Nakashima ◽  
Naoki Shino ◽  
Koichi Sasaki ◽  
Akihiro Hosokawa ◽  
...  

TAPPI Journal ◽  
2014 ◽  
Vol 13 (2) ◽  
pp. 17-25
Author(s):  
JUNMING SHU ◽  
ARTHAS YANG ◽  
PEKKA SALMINEN ◽  
HENRI VAITTINEN

The Ji’an PM No. 3 is the first linerboard machine in China to use multilayer curtain coating technology. Since successful startup at the end of 2011, further development has been carried out to optimize running conditions, coating formulations, and the base paper to provide a product with satisfactory quality and lower cost to manufacture. The key challenges include designing the base board structure for the desired mechanical strength, designing the surface properties for subsequent coating operations, optimizing the high-speed running of the curtain coater to enhance production efficiency, minimizing the amount of titanium dioxide in the coating color, and balancing the coated board properties to make them suitable for both offset and flexographic printing. The pilot and mill scale results show that curtain coating has a major positive impact on brightness, while smoothness is improved mainly by the blade coating and calendering conditions. Optimization of base board properties and the blade + curtain + blade concept has resulted in the successful use of 100% recycled fiber to produce base board. The optical, mechanical, and printability properties of the final coated board meet market requirements for both offset and flexographic printing. Machine runnability is excellent at the current speed of 1000 m/min, and titanium dioxide has been eliminated in the coating formulations without affecting the coating coverage. A significant improvement in the total cost of coated white liner production has been achieved, compared to the conventional concept of using virgin fiber in the top ply. Future development will focus on combining low cost with further quality improvements to make linerboard suitable for a wider range of end-use applications, including frozen-food packaging and folding boxboard.


Sign in / Sign up

Export Citation Format

Share Document