Thermal unimolecular decomposition of ethyl propionate behind reflected shock waves

1976 ◽  
Vol 72 (0) ◽  
pp. 1456 ◽  
Author(s):  
John A. Barnard ◽  
Alan T. Cocks ◽  
Trevor K. Parrott
Keyword(s):  
Shock Waves ◽  
Unimolecular Decomposition ◽  
Ethyl Propionate ◽  
Reflected Shock

Mass spectrometric studies of chemical reactions in shock waves: the thermal decomposition of nitrous oxide

1969 ◽  
Vol 47 (4) ◽  
pp. 521-538 ◽  
Author(s):  
S. C. Barton ◽  
J. E. Dove
Keyword(s):  
Thermal Decomposition ◽  
Shock Waves ◽  
Rate Coefficient ◽  
Mass Spectrometric Study ◽  
Mass Spectrometric ◽  
Unimolecular Decomposition ◽  
Reflected Shock ◽  
Secondary Reactions ◽  
Gas Reactions ◽  
Collision Mechanism

Apparatus for the mass spectrometric study of rapid gas reactions in reflected shock waves is described. This apparatus has been applied to the thermal decomposition of 2% N2O in Kr at total gas concentrations of about 1.6 × 10−6 mole cm−3, in the temperature range 1800 to 2800 °K. The principal products of the reaction were found to be N2, O2, NO, and O. The rate coefficient for the unimolecular decomposition of N2O was calculated from the experimental data, and the rates of the secondary reactions between O and N2O were estimated. The possibility of the occurrence of a "weak collision" mechanism in the unimolecular reaction of N2O is discussed.

The thermal unimolecular decomposition of 3,4-dihydro-2H-pyran behind reflected shock waves

1990 ◽  
Vol 165 (5) ◽  
pp. 383-385 ◽  
Author(s):  
K. Saito ◽  
K. Adachi ◽  
M. Watanabe ◽  
K. Shimofuji ◽  
A. Imamura
Keyword(s):  
Shock Waves ◽  
Unimolecular Decomposition ◽  
Reflected Shock

A New Method for Current ``Crowbar,'' Utilizing Reflected Shock Waves

1972 ◽  
Vol 43 (10) ◽  
pp. 1481-1481 ◽  
Author(s):  
Koichi Kasuya ◽  
Toshimitsu Murasaki
Keyword(s):  
Shock Waves ◽  
New Method ◽  
Reflected Shock
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