Re-determination of the standard electrode potential of zinc and mean molal activity coefficients for aqueous zinc chloride at 298.15 K

1976 ◽  
Vol 72 (0) ◽  
pp. 495 ◽  
Author(s):  
Lutfullah ◽  
Helen S. Dunsmore ◽  
Russell Paterson
Keyword(s):  
Activity Coefficients ◽  
Zinc Chloride ◽  
Electrode Potential ◽  
Standard Electrode Potential

Fundamentals of Electrochemistry

2021 ◽  
pp. 389-411
Author(s):  
Christopher O. Oriakhi
Keyword(s):  
Free Energy ◽  
Equilibrium Constant ◽  
Electrode Potential ◽  
Electrolytic Cell ◽  
Electrochemical Cells ◽  
Standard Electrode Potential ◽  
Cell Potential ◽  
Oxidation Reduction ◽  
Constant Determination

Fundamentals of Electrochemistry build on basic oxidation-reduction reactions and present an overview of their use in electrochemical cells. The construction and operation of a galvanic cell is described with cell diagrams including the function of the electrodes (cathode and anode). Also covered are the standard electrode potential and its applications, including calculations involving the standard electrode potential, the Gibbs free energy and the equilibrium constant, determination of the spontaneity in redox reactions and the dependence of cell potential on concentration (the Nernst equation). Finally a qualitative and quantitative overview of electrolysis is presented with a focus on predicting the products of electrolysis and the stoichiometry of electrolysis, which relates the charge flowing through an electrolytic cell to the amount of products formed at the electrodes.

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