Electron spin resonance spectra of the reaction products of copper(II) hydroxide suspensions in methanol with hydrogen peroxide and of polycrystalline copper(II) hydroxide and copper(II) peroxide

1973 ◽  
Vol 69 (0) ◽  
pp. 1523 ◽  
Author(s):  
Gerhard Vierke
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Spin Resonance ◽  
Electron Spin ◽  
Polycrystalline Copper ◽  
Reaction Products ◽  
Spin Resonance

Nitroxides as reaction intermediates

1982 ◽  
Vol 60 (12) ◽  
pp. 1414-1420 ◽  
Author(s):  
Hans Gunter Aurich
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Isopropyl Alcohol ◽  
High Reactivity ◽  
Reaction Intermediates ◽  
Reaction Products ◽  
Nitronyl Nitroxide ◽  
Reaction Conditions ◽  
Spin Resonance ◽  
Secondary Reactions

Vinyl nitroxides 4 are obtained by oxidation of the nitrones 3, as was shown by esr studies and by identification of the reaction products. The formation of 4d–f is even observed in oxidation of the hydroxylamines 1d–f, nitroxides 2d–f and nitrones 3d–f being the intermediates. The high reactivity of the vinyl nitroxides 4 at their β-position is illustrated by the reactions of 4a with various compounds affording the nitroxides 7–10, respectively. Compound 4c reacts with its precursor 3c to give 11, 12, or 13, depending on the reaction conditions. From oxidation of 3a, c, and e the dimerization products 5a, c, and e, respectively, could be isolated. Whereas further oxidation of 5d yields 6d, the acyl nitroxides 14a and c are formed in the oxidation of 5a and c, respectively.The formation of quinone 23 in the reaction of 2-methyl-2-nitrosopropane with potassium tert-butoxide in isopropyl alcohol in the presence of oxygen is discussed. The nitroxide 20 has been detected in the reaction mixture. Imines 24 react with nitrosobenzene giving nitroxides 26. These are further oxidized by nitrosobenzene to afford nitrones 27. Whereas 27a and b could be isolated, 27c and d undergo further reaction yielding the diimines 30c and d along with dinitrone 29.The formation and reactions of imino nitroxides 31 and of the nitronyl nitroxide 41 are discussed. Electron spin resonance studies revealed the high reactivity of the imidazolyl-1,3-dioxides 46 and the imidazolyl-1-oxides 50, which easily form radicals 47–49 and 51, respectively, which are derived from secondary reactions.

scholarly journals Electron Spin Resonance Detection of Hydrogen Peroxide as an Endothelium-Derived Hyperpolarizing Factor in Porcine Coronary Microvessels

2003 ◽  
Vol 23 (7) ◽  
pp. 1224-1230 ◽  
Author(s):  
Tetsuya Matoba ◽  
Hiroaki Shimokawa ◽  
Keiko Morikawa ◽  
Hiroshi Kubota ◽  
Ikuko Kunihiro ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Spin Resonance ◽  
Electron Spin ◽  
Spin Resonance ◽  
Resonance Detection

Electron spin resonance and fluorescence imaging assisted electrochemical approach for accurate and comprehensive monitoring of cellular hydrogen peroxide dynamics

The Analyst ◽  
2017 ◽  
Vol 142 (2) ◽  
pp. 316-325 ◽  
Author(s):  
Qi Xin ◽  
Qian Liu ◽  
Hameed Shah ◽  
Jian Ru Gong
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Spin Resonance ◽  
Fluorescence Imaging ◽  
Electron Spin ◽  
Electrochemical Approach ◽  
Spin Resonance ◽  
Analytical System

A new analytical system combining electrochemistry, ESR, and fluorescence imaging for accurately and comprehensively measuring the dynamics of cellular H2O2.

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