Mixed-valence dinuclear iron complexes with a nonadentate polypyridine ligand: high-spin iron(II)–low-spin iron(III)

Author(s):  
Yonezo Maeda ◽  
Kota Kawano ◽  
Takayuki Oniki
2019 ◽  
Vol 493 ◽  
pp. 127
Author(s):  
Avishek Jana ◽  
Brijesh K. Verma ◽  
Aditya Garai ◽  
Paturu Kondaiah ◽  
Akhil R. Chakravarty

1996 ◽  
Vol 25 (11) ◽  
pp. 933-934 ◽  
Author(s):  
Hideki Sugimoto ◽  
Yoshihito Hayashi ◽  
Chikako Koshi ◽  
Shuhei Fujinami ◽  
Masatatsu Suzuki ◽  
...  

1979 ◽  
Vol 41 (1) ◽  
pp. 25-30 ◽  
Author(s):  
Umberto Russo ◽  
Sandro Calogero ◽  
Nicola Burriesci ◽  
Michele Petrera

2013 ◽  
Vol 62 (10) ◽  
pp. 2122-2131 ◽  
Author(s):  
I. L. Fedushkin ◽  
A. A. Skatova ◽  
N. M. Khvoinova ◽  
A. N. Lukoyanov ◽  
G. K. Fukin ◽  
...  

2021 ◽  
Author(s):  
Daniel Kim ◽  
Daniel Wilson ◽  
Majed Fataftah ◽  
Brandon Mercado ◽  
Patrick Holland

We report the synthesis of two complexes featuring unsupported Fe–Fe bonds between a diketiminate/dialdiminate-coordinated iron site and a cyclopentadienyl dicarbonyl iron site. Mössbauer spectroscopy, SQUID magnetometry and computational analysis indicate that the most accurate electronic structure description is with the Fe(CO)2Cp site as low spin iron(0), and it acts as a Lewis base toward the high spin iron(II) of the LFe fragment which is a Lewis acid. In both compounds, the three-coordinate high-spin iron(II) site has large zero-field splitting (zfs), up to D = –50 cm–1.


2018 ◽  
Vol 483 ◽  
pp. 571-578 ◽  
Author(s):  
Avishek Jana ◽  
Brijesh K. Verma ◽  
Aditya Garai ◽  
Paturu Kondaiah ◽  
Akhil R. Chakravarty

1971 ◽  
pp. 112-168 ◽  
Author(s):  
N. N. Greenwood ◽  
T. C. Gibb

2017 ◽  
Vol 56 (18) ◽  
pp. 11030-11042 ◽  
Author(s):  
Rafał Grubba ◽  
Kinga Kaniewska ◽  
Łukasz Ponikiewski ◽  
Beata Cristóvão ◽  
Wiesława Ferenc ◽  
...  

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