Ligand-field stabilization energies of the first-row transition-metal dihalides and their bearing on the Irving–Williams rule

1995 ◽  
pp. 3483-3488 ◽  
Author(s):  
David A. Johnson ◽  
Peter G. Nelson
Keyword(s):  
Transition Metal ◽  
Ligand Field ◽  
Stabilization Energies

Phase stability of transition metal dichalcogenide by competing ligand field stabilization and charge density wave

2D Materials ◽  
2015 ◽  
Vol 2 (3) ◽  
pp. 035019 ◽  
Author(s):  
Santosh K C ◽  
Chenxi Zhang ◽  
Suklyun Hong ◽  
Robert M Wallace ◽  
Kyeongjae Cho
Keyword(s):  
Transition Metal ◽  
Charge Density ◽  
Phase Stability ◽  
Charge Density Wave ◽  
Density Wave ◽  
Ligand Field ◽  
Transition Metal Dichalcogenide

Ligand field stabilization energies and stereochemistry of early second and third row transition elements

1968 ◽  
Vol 21 (1) ◽  
pp. 9 ◽  
Author(s):  
R Colton ◽  
JH Canterford
Keyword(s):  
Periodic Table ◽  
Ligand Field ◽  
Transition Elements ◽  
Transition Series ◽  
Stabilization Energies

The elements of the second and third row transition series towards the left of the Periodic Table show clearly defined trends in their observed stereochemistries. These trends are summarized and an explanation for the experimental facts is suggested.

Magnetism, electronic spectra, and structure of transition metal alkoxides. I. methoxides and ethoxides of chromium(II), manganese(II), Iron(II), cobalt(II), nickel(II), copper(II), titanium(III), chromium(III), and iron(III)

1966 ◽  
Vol 19 (2) ◽  
pp. 207 ◽  
Author(s):  
RW Adams ◽  
E Bishop ◽  
RL Martin ◽  
G Winter
Keyword(s):  
Transition Metal ◽  
Spectral Data ◽  
Electronic Spectra ◽  
Magnetic Moments ◽  
Field Parameter ◽  
Ligand Field ◽  
Metal Alkoxides ◽  
Infinite Lattices ◽  
Ligand Field Parameter

The magnetic moments and electronic spectra are reported for the following divalent transition metal methoxides: Cr(OCH3)2, Mn(OCH3)2, Fe(OCH3)2, Co(OCH3)2, Ni(OCH3)2, and Cu(OCH3)2. These measurements when coupled with the involatility and insolubility of the compounds favour structures based on infinite lattices composed either of regular (Mn, Fe, Co, and Ni) or distorted (Cr and Cu) MO6 octahedra. The spectral data place the ligand field parameter, Δ, for the methoxide group very close to that of water.

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