Electrochemical generation of low-valent molybdenum tri-tertiary phosphine complexes: interactions with monophosphines and molecular nitrogen

1992 ◽  
pp. 2263 ◽  
Author(s):  
Jean Talarmin ◽  
Talib I. Al-Salih ◽  
Christopher J. Pickett ◽  
Gerald E. Bossard ◽  
T. Adrian George ◽  
...  
Keyword(s):  
Molecular Nitrogen ◽  
Tertiary Phosphine ◽  
Electrochemical Generation ◽  
Phosphine Complexes ◽  
Low Valent

ChemInform Abstract: TERTIARY PHOSPHINE COMPLEXES OF LOW-VALENT ZIRCONIUM AND THEIR PROPERTIES

1979 ◽  
Vol 10 (21) ◽  
Author(s):  
S. DATTA ◽  
S. S. WREFORD ◽  
R. P. BEATTY ◽  
T. J. MCNEESE
Keyword(s):  
Tertiary Phosphine ◽  
Phosphine Complexes ◽  
Low Valent

Tertiary phosphine complexes of low-valent zirconium and their properties

1979 ◽  
Vol 101 (4) ◽  
pp. 1053-1054 ◽  
Author(s):  
S. Datta ◽  
S. S. Wreford ◽  
R. P. Beatty ◽  
T. J. McNeese
Keyword(s):  
Tertiary Phosphine ◽  
Phosphine Complexes ◽  
Low Valent

The Stereospecific Synthesis of Neutral and Cationic Tertiary Phosphine Complexes of Platinum(II)

1974 ◽  
Vol 52 (4) ◽  
pp. 692-695 ◽  
Author(s):  
Keith R. Dixon ◽  
Kenneth C. Moss ◽  
Martin A. R. Smith
Keyword(s):  
Synthetic Methods ◽  
Stereospecific Synthesis ◽  
Tertiary Phosphine ◽  
Phosphine Complexes ◽  
Square Planar ◽  
Cleavage Reactions ◽  
Cis And Trans

Stereospecific synthetic methods for the preparation of complexes of the type cis- and trans[PtClL(PEt3)2]+ and cis-[PtClX(PEt3)2] have been developed. Preparations of complexes where L = py, PPh3, PClPh2, or P(OPh)3 and X = SCN, NO2, NO3, N3, NCO, or Br are described and it is shown that bridge cleavage reactions in square planar platinum(II) complexes occur with retention of stereo chemistry.

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