Catalytic reduction of nitrous oxide to dinitrogen by carbon monoxide using Group 8 metal carbonyl anions

1992 ◽  
pp. 1025 ◽  
Author(s):  
Chen-Shun Li ◽  
Kin-Seng Sun ◽  
Chien-Hong Cheng
Keyword(s):  
Carbon Monoxide ◽  
Nitrous Oxide ◽  
Catalytic Reduction ◽  
Metal Carbonyl

REVIEW OF CHEMICAL REACTIONS IN THE NO REDUCTION BY CO ON PLATINUM/ALUMINA CATALYSTS

2012 ◽  
Vol 19 (01) ◽  
pp. 1230001 ◽  
Author(s):  
ANAND SRINIVASAN ◽  
CHRISTOPHER DEPCIK
Keyword(s):  
Nitric Oxide ◽  
Carbon Monoxide ◽  
Nitrous Oxide ◽  
Internal Combustion Engines ◽  
Catalytic Reduction ◽  
Platinum Group Metals ◽  
Combustion Engines ◽  
No Reduction By Co ◽  
Nitrous Oxide Production ◽  
Global Reaction

The emissions of nitric oxide and carbon monoxide from internal combustion engines generate a large impact on the environment and on people's health. Catalytic reduction of these species using platinum group metals has already shown significant potential for emissions control. Since catalysts often use carbon monoxide to reduce nitric oxide in these devices, accurate models of their interaction are required to advance catalyst simulations in order to meet increasingly stringent emissions regulations. As a result, this paper reviews the literature of the NO–CO reaction over platinum in order to develop more precise detailed and global reaction mechanisms for use in exhaust after-treatment modeling activities. Moreover, it is found that the reaction between NO and CO over platinum yields carbon dioxide and nitrogen as main products and nitrous oxide as an important side product. Hence, this paper additionally describes the mechanism for nitrous oxide production in advance of greenhouse gas regulations.

Catalytic reduction of nitrous oxide with carbon monoxide over calcined Co–Mn–Al hydrotalcite

2008 ◽  
Vol 137 (2-4) ◽  
pp. 385-389 ◽  
Author(s):  
K. Pacultová ◽  
L. Obalová ◽  
F. Kovanda ◽  
K. Jirátová
Keyword(s):  
Carbon Monoxide ◽  
Nitrous Oxide ◽  
Catalytic Reduction

Kinetics of catalytic reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst

1983 ◽  
Vol 48 (11) ◽  
pp. 3202-3208 ◽  
Author(s):  
Zdeněk Musil ◽  
Vladimír Pour
Keyword(s):  
Carbon Monoxide ◽  
Nitrogen Oxide ◽  
Rate Equation ◽  
Catalytic Reduction ◽  
Zero Order ◽  
Spectroscopic Measurements ◽  
First Order ◽  
Ir Spectroscopic ◽  
Kinetics Of ◽  
Al2o3 Catalyst

The kinetics of the reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst (8.36 mass % CuO) were determined at temperatures between 413 and 473 K. The reaction was found to be first order in NO and zero order in CO. The observed kinetics are consistent with a rate equation derived from a mechanism proposed on the basis of IR spectroscopic measurements.

Dichlorosilylene: Rate constant for reaction with carbon monoxide and nitrous oxide

1989 ◽  
Vol 11 (3) ◽  
pp. 235-244 ◽  
Author(s):  
V. Sandhu ◽  
O. P. Strausz ◽  
T. N. Bell
Keyword(s):  
Carbon Monoxide ◽  
Nitrous Oxide ◽  
Rate Constant
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