Kinetics of dissociation of H2 from transition-metal polyhydride complexes

1991 ◽  
pp. 717 ◽  
Author(s):  
Jack Halpern ◽  
Lisheng Cai ◽  
Peter J. Desrosiers ◽  
Zerong Lin
Keyword(s):  
Transition Metal ◽  
Kinetics Of

The influence of transition metal oxides on the kinetics of Li2O2oxidation in Li–O2batteries: high activity of chromium oxides

2014 ◽  
Vol 16 (6) ◽  
pp. 2297-2304 ◽  
Author(s):  
Koffi P. C. Yao ◽  
Yi-Chun Lu ◽  
Chibueze V. Amanchukwu ◽  
David G. Kwabi ◽  
Marcel Risch ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
High Activity ◽  
Transition Metal Oxides ◽  
Chromium Oxides ◽  
Kinetics Of

The electrode kinetics of transition metal salene complexes

1984 ◽  
Vol 163 (1-2) ◽  
pp. 189-198 ◽  
Author(s):  
Andrzej Kapturkiewicz ◽  
Barbara Behr
Keyword(s):  
Transition Metal ◽  
Electrode Kinetics ◽  
Kinetics Of

On stability and kinetics of Li-rich transition metal oxides and oxyfluorides

2020 ◽  
Vol 8 (16) ◽  
pp. 7956-7967 ◽  
Author(s):  
Holger Euchner ◽  
Jin Hyun Chang ◽  
Axel Groß
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Kinetics Of

Stability and kinetics of Li-rich transition metal oxides and oxyfluorides are extensively studied by DFT.

scholarly journals Recent Advances in Nanostructured Transition Metal Carbide- and Nitride-Based Cathode Electrocatalysts for Li–O2 Batteries (LOBs): A Brief Review

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2106
Author(s):  
K. Karuppasamy ◽  
K. Prasanna ◽  
Vasanth Rajendiran Jothi ◽  
Dhanasekaran Vikraman ◽  
Sajjad Hussain ◽  
...  
Keyword(s):  
Transition Metal ◽  
Rational Design ◽  
Rate Capability ◽  
High Energy ◽  
High Energy Density ◽  
Electrochemical Kinetics ◽  
Transition Metal Carbide ◽  
Round Trip ◽  
Slow Kinetics ◽  
Kinetics Of

A large volume of research on lithium–oxygen (Li–O2) batteries (LOBs) has been conducted in the recent decades, inspired by their high energy density and power density. However, these future generation energy-storage devices are still subject to technical limitations, including a squat round-trip efficiency and a deprived rate-capability, due to the slow-moving electrochemical kinetics of both the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) over the surface of the cathode catalyst. Because the electrochemistry of LOBs is rather complex, only a limited range of cathode catalysts has been employed in the past. To understand the catalytic mechanisms involved and improve overall cell performance, the development of new cathode electrocatalysts with enhanced round-trip efficiency is extremely important. In this context, transition metal carbides and nitrides (TMCs and TMNs, respectively) have been explored as potential catalysts to overcome the slow kinetics of electrochemical reactions. To provide an accessible and up-to-date summary for the research community, the present paper reviews the recent advancements of TMCs and TMNs and its applications as active electrocatalysts for LOBs. In particular, significant studies on the rational design of catalysts and the properties of TMC/TMN in LOBs are discussed, and the prospects and challenges facing the continued development of TMC/TMN electrocatalysts and strategies for attaining higher OER/ORR activity in LOBs are presented.

Sign in / Sign up

Export Citation Format

Share Document