Silver macrocyclic complexes: synthesis, crystal structures and redox properties of [Ag([18]aneN2S4)]PF6and [Ag(Me2[18]aneN2S4)]BPh4([18]aneN2S4= 1,4,10,13-tetrathia-7,16-diazacyclooctadecane, Me2[18]aneN2S4= 7,16-dimethyl-1,4,10,13-tetrathia-7,16-diazacyclooctadecane)

1991 ◽  
pp. 615-620 ◽  
Author(s):  
Alexander J. Blake ◽  
Gillian Reid ◽  
Martin Schröder
Keyword(s):  
Crystal Structures ◽  
Redox Properties ◽  
Macrocyclic Complexes

Synthesis, crystal structures, Mössbauer spectra, and redox properties of binuclear and tetranuclear iron-sulfur nitrosyl clusters

2000 ◽  
Vol 49 (3) ◽  
pp. 444-451 ◽  
Author(s):  
N. A. Sanina ◽  
I. I. Chuev ◽  
S. M. Aldoshin ◽  
N. S. Ovanesyan ◽  
V. V. Strelets ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Mössbauer Spectra ◽  
Redox Properties ◽  
Mossbauer Spectra ◽  
Iron Sulfur

Tuning of Redox Properties for the Design of Ruthenium Anticancer Drugs:  Part 2. Syntheses, Crystal Structures, and Electrochemistry of Potentially Antitumor [RuIII/IICl6-n(Azole)n]z(n= 3, 4, 6) Complexes†

2005 ◽  
Vol 44 (19) ◽  
pp. 6704-6716 ◽  
Author(s):  
Erwin Reisner ◽  
Vladimir B. Arion ◽  
Anna Eichinger ◽  
Norbert Kandler ◽  
Gerald Giester ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Anticancer Drugs ◽  
Redox Properties

scholarly journals New Copper and Oxomolybdate Robson-Type Polynuclear Macrocyclic Complexes: Structure, Spectroscopy, and Electrochemical Properties

2015 ◽  
Vol 2015 ◽  
pp. 1-9
Author(s):  
Marcelo Carpes Nunes ◽  
Marcos Antonio Ribeiro ◽  
Fábio Souza Nunes
Keyword(s):  
Electrochemical Properties ◽  
Macrocyclic Ligand ◽  
Metal Cations ◽  
Redox Properties ◽  
Macrocyclic Complexes ◽  
Molecular Structures ◽  
Polynuclear Complexes ◽  
Unique Mode ◽  
Macrocycle Ligand ◽  
Mode Of Coordination

The polynuclear complexes [Mo3O8(tidf)]·dmso·2H2O (1) and [{Cu2(tidf)}2(μ-Mo8O24)] (2) (tidf2−is a symmetrical tetraiminodiphenolate Robson-type macrocyclic ligand) were prepared from equimolar combinations of [Mg2(tidf)](NO3)2·4H2O, [MoO2Cl2(dmso)2] (for1) and complex1and Cu(ClO4)2·4H2O (for2) in acetonitrile. Molecular structures of both complexes were determined and showed atypical modes of coordination. A significant observation was the remarkable flexibility of the macrocycle ligand that effectively accommodated the steric demands of metal cations and the packing forces and showed a unique mode of coordination. Spectroscopic (UV-vis and FTIR) and redox properties are discussed.

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