Reactivity of trinuclear ruthenium complexes involving bis(diphenylphosphino)methane (dppm) as a bridging ligand: facile declusterification of [Ru3(CO)8(µ-dppm-PP′)2] in the presence of iodine and the crystal structure of [Ru2(µ-I)2(CO)4(µ-dppm-PP′)]

1986 ◽  
pp. 899-901 ◽  
Author(s):  
Anne Colombie ◽  
Guy Lavigne ◽  
Jean-Jacques Bonnet
Keyword(s):  
Crystal Structure ◽  
Ruthenium Complexes ◽  
Bridging Ligand

scholarly journals Crystal structure of 2-[bis(benzylsulfanyl)methyl]-6-methoxyphenol

2020 ◽  
Vol 76 (4) ◽  
pp. 484-487
Author(s):  
Abhinav Raghuvanshi ◽  
Lena Knauer ◽  
Lydie Viau ◽  
Michael Knorr ◽  
Carsten Strohmann
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Coordination Chemistry ◽  
Title Compound ◽  
Dihedral Angles ◽  
Orthorhombic Space Group ◽  
Bridging Ligand ◽  
Compound C ◽  
Unit Form ◽  
Phenyl Rings

The title compound, C22H22O2S2, 1, represents an example of an ortho-vanillin-based functionalized dithioether, which could be useful as a potential chelating ligand or bridging ligand for coordination chemistry. This dithioacetal 1 crystallizes in the orthorhombic space group Pbca. The phenyl rings of the benzyl groups and that of the vanillin unit form dihedral angles of 35.38 (6) and 79.77 (6)°, respectively. The crystal structure, recorded at 100 K, displays both weak intramolecular O—H...O and intermolecular O—H...S hydrogen bonding.

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