Complexes of molybdenum-(II) and -(IV) and tungsten(II) with sterically hindered thiolate ligands. Synthesis, reactivity, and X-ray crystal structures of [PPH4][Mo(SC6H2Pri 3,-2,4,6)3(CO)2] and [Mo(NNPh)(SC6H2Pri 3-2,4,6)3(NCMe)]

1985 ◽  
pp. 2639 ◽  
Author(s):  
Philip J. Blower ◽  
Jonathan R. Dilworth ◽  
John Hutchinson ◽  
Terry Nicholson ◽  
Jon A. Zubieta
Keyword(s):  
Crystal Structures ◽  
X Ray ◽  
Thiolate Ligands ◽  
Sterically Hindered ◽  
And Tungsten

2,2′:6′,2″-Terpyridine complexes of molybdenum(II) and tungsten(II). X-ray crystal structures of [MoI(CO)(terpy)(η2-PhC2Ph)]I and [WI(terpy)(η2-PhC2Ph)2]I·CDCl3

2000 ◽  
Vol 604 (2) ◽  
pp. 191-196 ◽  
Author(s):  
Nicholas Aimeloglou ◽  
Paul K. Baker ◽  
Michael G.B. Drew ◽  
Bjoern Glaeser ◽  
Fiona Holland ◽  
...  
Keyword(s):  
Crystal Structures ◽  
X Ray ◽  
And Tungsten

Chemistry of molybdenum and tungsten bis[hydrazido(2-1)] complexes. Preparations and x-ray crystal structures of [Mo(NNMePh)2(S2CNMe2)2], [Mo(NNPh2)2(S2CNMe2)2]Me2CO, [MoCl(NNMe2)2(PPh3)2]BPh4.CH2Cl2, and [Mo(NNMe2)2(bpy)2][BPh4]2.CH2Cl2

1982 ◽  
Vol 21 (6) ◽  
pp. 2383-2391 ◽  
Author(s):  
Joseph. Chatt ◽  
Brian A. L. Crichton ◽  
Jonathan R. Dilworth ◽  
Phillip. Dahlstrom ◽  
Robert. Gutkoska ◽  
...  
Keyword(s):  
Crystal Structures ◽  
X Ray ◽  
And Tungsten

Pentamethylcyclopentadienyl molybdenum and tungsten carbene complexes. X-Ray crystal structures of cis- and trans-[Mol(CO)2{C(CH2)3O}(η-C5Me5)]

1988 ◽  
pp. 1449-1456 ◽  
Author(s):  
Neil A. Bailey ◽  
Deborah A. Dunn ◽  
Clare N. Foxcroft ◽  
Gavin R. Harrison ◽  
Mark J. Winter ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Carbene Complexes ◽  
X Ray ◽  
Cis And Trans ◽  
And Tungsten

scholarly journals Synthese von Stickstoff- und Chlor-verbrückten Indiumorganylen. Die Kristallstrukturen von [Mes(Cl)InN(SiMe3)2]2 und {i-Pr2In[N(H)t-Bu]2In(Cl)i-Pr} / Synthesis of Nitrogen- and Chloro-Bridged Organoindium Compounds. The Crystal Structures of [Mes(Cl)InN(SiMe3)2]2 and {i-Pr2In[N(H)t-Bu]2In(Cl)i-Pr}

1991 ◽  
Vol 46 (6) ◽  
pp. 753-761 ◽  
Author(s):  
Bernhard Neumüller
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Crystal Structures ◽  
Alkyl Aryl ◽  
X Ray ◽  
Sterically Hindered

[(PhCH2)2InN(H)t-Bu]2 (3) and [PhCH2(Cl)InN(SiMe3)2]2 (4) have been prepared by the reaction of (PhCH2)2InCl with LiN(H)t-Bu and of PhCH2InCl2 with NaN(SiMe3)2, respectively. 3 could be isolated in two isomers, while 4 forms only one chloro-bridged isomer in solution and in the solid state. The possibility of a chloro-bridged alkyl(aryl)chloroindium amide is also realized in [Mes(Cl)InN(SiMe3)2]2 (2), as shown by X-ray analysis. The reaction of a 1:1-mixture of i-Pr2InCl/i-PrInCl2 with LiN(H)t-Bu leads to all three possible compounds: [i-Pr(Cl)InN(H)t-Bu]2 (1), {i-Pr2In[N(H)t-Bu]2In(Cl)i-Pr} (5), and [i-Pr2InN(H)t-Bu]2 (6). Two isomers of the new compound 5 are detectable in solution. The crystal structure has been determined for the less sterically hindered isomer 5a, which forms hydrogen-bridged (Cl-H-N-bridge) infinite chains along the c-axis.

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