Phosphorus–phosphorus bond cleavage in the cage molecule P4S3: synthesis and crystal structure of the trinuclear platinum complex [{Pt(µ-P4S3)(PPh3)}3]·C6H6

1985 ◽  
pp. 291-295 ◽  
Author(s):  
Massimo Di Vaira ◽  
Maurizio Peruzzini ◽  
Piero Stoppioni
Keyword(s):  
Crystal Structure ◽  
Bond Cleavage ◽  
Platinum Complex ◽  
Synthesis And Crystal Structure ◽  
Cage Molecule

Cluster Chemistry. XLI. P-C Bond Cleavage Reactions of Ru3(µ-dppm)(CO)10. Synthesis and Crystal Structure of Ru3[µ3-PPhCH2PPh(C6H4)](CO)9

1985 ◽  
Vol 38 (9) ◽  
pp. 1301 ◽  
Author(s):  
MI Bruce ◽  
PA Humphrey ◽  
BW Skelton ◽  
AH White ◽  
ML Williams
Keyword(s):  
Crystal Structure ◽  
Bond Cleavage ◽  
Title Complex ◽  
Cluster Chemistry ◽  
Synthesis And Crystal Structure ◽  
Cleavage Reactions

Thermolysis of Ru3(μ- dppm )(CO)10 (1) results in cyclometallation and dephenylation to give the title complex. This complex is also formed, together with Ru3(μ-H)(μ3-PPhCH2PPh2(CO)9, from reaction between (1) with HC5(CO2Me)5.

scholarly journals Mechanochemical synthesis and crystal structure of a 1:2 co-crystal of 1,3,6,8-tetraazatricyclo[4.3.1.13,8]undecane (TATU) and 4-chloro-3,5-dimethylphenol

2016 ◽  
Vol 72 (11) ◽  
pp. 1651-1653 ◽  
Author(s):  
Augusto Rivera ◽  
Jicli José Rojas ◽  
John Sadat-Bernal ◽  
Jaime Ríos-Motta ◽  
Michael Bolte
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Crystal Packing ◽  
Asymmetric Unit ◽  
Synthesis And Crystal Structure ◽  
Free Treatment ◽  
Centroid Distance ◽  
Benzene Rings ◽  
Cage Molecule ◽  
Aminal Cage

Solvent-free treatment of 1,3,6,8-tetraazatricyclo[4.3.1.13,8]undecano (TATU) with 4-chloro-3,5-dimethylphenol led to the formation of the title co-crystal, C7H14N4·2C8H9ClO. The asymmetric unit contains one aminal cage molecule and two phenol molecules linkedviatwo O—H...N hydrogen bonds. In the aminal cage, the N–CH2–CH2–N unit is slightly distorted from asynperiplanar geometry. Aromatic π–π stacking between the benzene rings from two different neighbouring phenol molecules [centroid–centroid distance = 4.0570 (11) Å] consolidates the crystal packing.

Synthesis and crystal structure analysis of ferrocenylthiosemicarbazone complexes of palladium(II): Unusual σPd–C bond cleavage

Polyhedron ◽  
2006 ◽  
Vol 25 (6) ◽  
pp. 1449-1456 ◽  
Author(s):  
Marta Mariño ◽  
Eduardo Gayoso ◽  
José M. Antelo ◽  
Luis A. Adrio ◽  
Jesús J. Fernández ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Structure Analysis ◽  
Bond Cleavage ◽  
Crystal Structure Analysis ◽  
Synthesis And Crystal Structure

Synthesis and crystal structure of [MnL(μ-Cl)MnCl3]·H2O L=N, N'-bis(2'-pyridine)methyl-1,10-phenanthroline-2,9-dimethanamine

2002 ◽  
Vol 2002 (3) ◽  
pp. 120-121
Author(s):  
Tian Fu Liu ◽  
Hua Kuan Lin ◽  
Shou Rong Zhu ◽  
Zhong Ming Wang ◽  
Hong Gen Wang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure
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