The resolution of chlorine and bromine isotope shifts in the 31P nuclear magnetic resonance spectra of PCl3 and PBr3

Author(s):  
Malcolm J. Buckingham ◽  
Geoffrey E. Hawkes ◽  
Ismail M. Ismail ◽  
Peter J. Sadler
1975 ◽  
Vol 53 (12) ◽  
pp. 1829-1832 ◽  
Author(s):  
Gerald W. Buchanan ◽  
Richard S. Ozubko

13C n.m.r. signal assignments are presented for the carcinogenic polynuclear hydrocarbon benzo[a]pyrene. In addition to selective 1H decoupling, valuable information is obtained from the magnitudes of the α-, β-, and "peri" deuterium isotope shifts in the 1,3,6-trideuterio analog. The applicability of the model compound approach to signal assignment is explored in detail.


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