Bis adducts of phthalocyaninatoiron(II) with Group 6 axial donor atoms. Crystal and molecular structure of sulphur-bonded bis(dimethyl sulphoxide)phthalocyaninatoiron(II)–dimethyl sulphoxide (1/2)

1980 ◽  
pp. 1965-1969 ◽  
Author(s):  
Fausto Calderazzo ◽  
Guido Pampaloni ◽  
Dario Vitali ◽  
Ines Collamati ◽  
Giulia Dessy ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Dimethyl Sulphoxide ◽  
Group 6

Crystal and molecular structure of hexakis(tert-butoxo)dialuminum. Comments on the extent of M-O .pi. bonding in Group 6 and Group 13 alkoxides

1991 ◽  
Vol 30 (5) ◽  
pp. 1020-1024 ◽  
Author(s):  
Roger H. Cayton ◽  
Malcolm H. Chisholm ◽  
Ernest R. Davidson ◽  
Vincent F. DiStasi ◽  
Ping. Du ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Group 13 ◽  
Group 6

Remote and α-Thio Carbene Complexes Derived from an Oxazolinylsubstituted Thiophene

2012 ◽  
Vol 67 (6) ◽  
pp. 509-518 ◽  
Author(s):  
Liliana Dobrzańska ◽  
Gerrit R. Julius ◽  
Elzet Stander-Grobler ◽  
Yolanda Burger (neé Stander) ◽  
Stefan D. Nogai ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Thiophene Ring ◽  
Group 14 ◽  
Carbene Complexes ◽  
Spectroscopic Measurements ◽  
Group 6 ◽  
Structure Determinations ◽  
Oxidative Substitution ◽  
New Compounds

Transmetallation and oxidative substitution were utilized to prepare examples of group 14, group 6 and group 10 complexes from lithiated or chlorinated 4,4-dimethyl-2-(2-thienyl) oxazoline or its N-alkylated analogs. Two of the product types (2and 5) can be classified as a-thio or remote carbene complexes, depending on the position (3- or 5-) of attachment to the substituted thiophene ring. Spectroscopic measurements as well as crystal and molecular structure determinations clarified the bonding within the new compounds.

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