Mechanisms of organometallic reactions. Part II. Kinetics of the reaction of acetonitrile with tricarbonyl-(cycloheptatriene) and -(arene) complexes of metals in Group VI

1974 ◽  
pp. 428 ◽  
Author(s):  
Khaliel M. Al-Kathumi ◽  
Leon A. P. Kane-Maguire
Keyword(s):  
Arene Complexes ◽  
Group Vi ◽  
Organometallic Reactions ◽  
Kinetics Of

Kinetics of reactions of chlorine atom/arene complexes withn-heptane

1997 ◽  
Vol 62 (2) ◽  
pp. 225-232
Author(s):  
Sándor Förgeteg ◽  
Lajos Zalotai
Keyword(s):  
Chlorine Atom ◽  
Arene Complexes ◽  
Kinetics Of

Effect of Laser Heating on Compositions of Films Deposited from the Metal Hexacarbonyls

1990 ◽  
Vol 201 ◽  
Author(s):  
K. A. Singmaster ◽  
F. A. Houle
Keyword(s):  
Systematic Study ◽  
Laser Heating ◽  
Metal Films ◽  
Crystal Surfaces ◽  
Group Vi ◽  
Single Crystal Surfaces ◽  
Spatially Inhomogeneous ◽  
Metal Hexacarbonyls ◽  
Kinetics Of ◽  
Deposited Films

AbstractA systematic study of the composition of metal films thermally deposited by laser heating (cw 514 nm) of the group VI hexacarbonyls is described. The films are found to contain significantly lower levels of carbon and oxygen than photochemically deposited films, and are spatially inhomogeneous. Estimates of temperature to determine the extent of laser heating permit the kinetics of this process to be compared to ∞ desorption from single crystal surfaces.

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