Unstable intermediates. Part CVI. γ-Irradiation of frozen aqueous solutions of alkali-metal cyanides

1972 ◽  
pp. 185-187 ◽  
Author(s):  
I. S. Ginns ◽  
M. C. R. Symons
Keyword(s):  
Alkali Metal ◽  
Aqueous Solutions ◽  
Γ Irradiation ◽  
Metal Cyanides

Radiothermal radiation method for aqueous solutions

2021 ◽  
Author(s):  
L.A. Morozova ◽  
S.V. Savel’ev
Keyword(s):  
Dielectric Properties ◽  
Alkali Metal ◽  
Thermal Radiation ◽  
Aqueous Solutions ◽  
Physical Properties ◽  
Dielectric Constants ◽  
Water Molecules ◽  
Absorption Coefficients ◽  
Basic Substance ◽  
High Dilutions

For the first time, an ultra-high-sensitivity method for measuring radio-thermal radiation was developed and used in practice in order to establish the difference in the physical properties of aqueous solutions of substances in the millimeter region of the spectrum. The method is used to study the dynamics of the dielectric properties of aqueous solutions depending on the composition of the base substance and its concentration. The dynamics of dielectric properties establishes a one-to-one correspondence between the number and concentration of ions of the dissolved basic substance contained in water and the number of water molecules involved in cooperative interaction, which gives a consistent microscopic picture of ion-water cooperative interactions in the studied aqueous solutions of K2SO4 and Cs2SO4. The density of water molecules perturbed by the ions of the base substance contained in the hydration shell at normal concentrations is proportional to the number of ions, while the transition to weaker solutions leads to the creation of multilayer hydration shells. This means that the number of perturbed water molecules, depending on the number of ions, increases according to a law different from linear. In accordance with the experimental data, the values of the absorption coefficients of aqueous solutions were determined in a wide range of concentrations for alkali metal sulfates. It is noted that alkali metal sulfates have physical properties that generalize the dynamics of dielectric constants depending on the concentration of the base substance. A monotonic increase in the values of the absorption coefficients of solutions with a decrease in the concentration of basic substances in the region of high dilutions was established with individual dynamics for each basic substance, reflecting the total hydration changes in salt solutions. Research has shown that the proposed method for measuring radio-thermal radiation fixes a significant difference in the values of the dielectric constants of aqueous solutions at high dilutions from their values for water.

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