Satellite structure in the photoelectron spectra of transition metal compounds ionized in the K shell of the metal ion

1975 ◽  
Vol 60 ◽  
pp. 30 ◽  
Author(s):  
Thomas A. Carlson
Keyword(s):  
Transition Metal ◽  
Metal Ion ◽  
Transition Metal Compounds ◽  
Photoelectron Spectra ◽  
Metal Compounds ◽  
Satellite Structure

First-row transition metal compounds for aqueous metal ion batteries

2021 ◽  
Author(s):  
Mengmeng Zhou ◽  
Xinjun Huang ◽  
Xiaomeng Tian ◽  
Baohua Jia ◽  
Hongge Pan ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Ion ◽  
Transition Metal Compounds ◽  
Metal Compounds

scholarly journals Density-Based Descriptors of Redox Reactions Involving Transition Metal Compounds as a Reality-Anchored Framework: A Perspective

Molecules ◽  
2021 ◽  
Vol 26 (18) ◽  
pp. 5541
Author(s):  
Daniel Koch ◽  
Mohamed Chaker ◽  
Manabu Ihara ◽  
Sergei Manzhos
Keyword(s):  
Transition Metal ◽  
Metal Ion ◽  
Redox Reactions ◽  
Rational Design ◽  
Chemical Properties ◽  
Transition Metal Ions ◽  
Blind Spot ◽  
Transition Metal Compounds ◽  
Metal Compounds ◽  
Active Transition

Description of redox reactions is critically important for understanding and rational design of materials for electrochemical technologies, including metal-ion batteries, catalytic surfaces, or redox-flow cells. Most of these technologies utilize redox-active transition metal compounds due to their rich chemistry and their beneficial physical and chemical properties for these types of applications. A century since its introduction, the concept of formal oxidation states (FOS) is still widely used for rationalization of the mechanisms of redox reactions, but there exists a well-documented discrepancy between FOS and the electron density-derived charge states of transition metal ions in their bulk and molecular compounds. We summarize our findings and those of others which suggest that density-driven descriptors are, in certain cases, better suited to characterize the mechanism of redox reactions, especially when anion redox is involved, which is the blind spot of the FOS ansatz.

He-I photoelectron spectra of some d 0 transition metal compounds

1974 ◽  
Vol 70 ◽  
pp. 1895 ◽  
Author(s):  
Peter Burroughs ◽  
Stephen Evans ◽  
Andrew Hamnett ◽  
Anthony F. Orchard ◽  
Neville V. Richardson
Keyword(s):  
Transition Metal ◽  
Transition Metal Compounds ◽  
Photoelectron Spectra ◽  
Metal Compounds

scholarly journals Density-based Descriptors of Redox Reactions Involving Transition Metal Compounds as a Reality-anchored Framework: A Perspective

2021 ◽  
Author(s):  
Daniel Koch ◽  
Mohamed Chaker ◽  
Manabu Ihara ◽  
Sergei Manzhos
Keyword(s):  
Transition Metal ◽  
Metal Ion ◽  
Redox Reactions ◽  
Rational Design ◽  
Chemical Properties ◽  
Transition Metal Ions ◽  
Blind Spot ◽  
Transition Metal Compounds ◽  
Metal Compounds ◽  
Active Transition

Description of redox reactions is critically important for understanding and rational design of materials for electrochemical technologies including metal-ion batteries, catalytic surfaces, or redox-flow cells. Most of these technologies utilize redox-active transition metal compounds due to their rich chemistry and their beneficial physical and chemical properties for these types of applications. A century since its introduction, the concept of formal oxidation states (FOS) is still widely used for rationalization of the mechanisms of redox reactions, but there exists a well-documented discrepancy between FOS and the electron density-derived charge states of transition metal ions in their bulk and molecular compounds. We summarize our findings and those of others which suggest that density-driven descriptors are in certain cases better suited to characterize the mechanism of redox reactions, especially when anion redox is involved, which is the blind spot of the FOS ansatz.

Sign in / Sign up

Export Citation Format

Share Document