Collision complex dynamics in alkali halide exchange reactions

1973 ◽  
Vol 55 ◽  
pp. 80 ◽  
Author(s):  
P. Brumer ◽  
M. Karplus
Keyword(s):  
Alkali Halide ◽  
Complex Dynamics ◽  
Exchange Reactions ◽  
Collision Complex ◽  
Halide Exchange

Regioselective Palladium(0)-Catalyzed Cross-Coupling Reactions and Metal-Halide Exchange Reactions of Tetrabromothiophene: Optimization, Scope and Limitations

2009 ◽  
Vol 351 (10) ◽  
pp. 1595-1609 ◽  
Author(s):  
Đǎng Thanh Tùng ◽  
Đǎng Thanh Tuân ◽  
Nasir Rasool ◽  
Alexander Villinger ◽  
Helmut Reinke ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Metal Halide ◽  
Coupling Reactions ◽  
Exchange Reactions ◽  
Cross Coupling Reactions ◽  
Halide Exchange

Reactions of Alkyl Halides in Fused Salt Media

1971 ◽  
Vol 49 (1) ◽  
pp. 1-6 ◽  
Author(s):  
R. A. Bailey ◽  
S. F. Prest
Keyword(s):  
Organic Molecules ◽  
Product Distribution ◽  
Exchange Reactions ◽  
Cyclization Reactions ◽  
Composition Effects ◽  
Carbonium Ion ◽  
Product Distributions ◽  
Halide Exchange ◽  
Melt Composition ◽  
Acid Character

Passage of C1 to C5 haloalkanes through SnCl2–KCl melts results in halide exchange reactions, alkene formation, and rearrangement (including cyclization) reactions of the organic molecules. Relative reactivities, product distributions and melt composition effects are consistent with a carbonium ion mechanism in which the melt functions as a halide ion acceptor. Some control of product distribution by choice of Lewis acid character of the melt seems possible.

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