On the Nature of Solvothermally Synthesized Carbon Dots

Author(s):  
Sergio Ramírez-Barroso ◽  
Alejandra Jacobo-Martín ◽  
Iván Navarro-Baena ◽  
Jaime J. Hernandez ◽  
Cristina Navio ◽  
...  

Due to their facile synthesis, biocompatibility, high apparent photoluminescence (PL) quantum yield and applications in photocatalysis, sensing and biomarkers carbon nanodots (CNDs) have been investigated intensively in recent years. Solvothermal...

RSC Advances ◽  
2020 ◽  
Vol 10 (55) ◽  
pp. 33483-33489
Author(s):  
Guohua Dong ◽  
Kun Lang ◽  
He Ouyang ◽  
Wenzhi Zhang ◽  
Liming Bai ◽  
...  

Nitrogen/phosphorus-doped carbon dots (N, P-CDs) with a quantum yield as high as 76.5% were synthesized by carbonizing maize starch via a facile ethanol solvothermal approach and utilized for the detection of Fe3+.


2018 ◽  
Vol 9 (1) ◽  
pp. 107 ◽  
Author(s):  
Sakeena Quraishi ◽  
Sven Plappert ◽  
Bernhard Ungerer ◽  
Philip Taupe ◽  
Wolfgang Gindl-Altmutter ◽  
...  

Green and facile approaches aiming at the manufacture of biocompatible paper-based optical sensors reporting the presence of photoluminescence (PL) modulating compounds is an emerging field of research. This study investigates the preparation of bacterial cellulose nanopaper containing covalently immobilized carbon dots for potential biosensing applications. Preliminary work of this feasibility study included TEMPO-mediated ((2,2,6,6-tetramethylpiperidin-1-yl)oxyl-mediated) oxidation and nanofibrillation of bacterial cellulose (TOBC) on the one hand as well as synthesis and comparative analysis of different types of carbon dots (CDs) on the other hand. The two source materials of the targeted functional nanopaper were finally linked to each other by two different N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride/ N-hydroxysuccinimide (EDC/NHS) coupling approaches to clarify whether grafting of CDs prior to or after TOBC paper formation would be the method of choice. Synthesis of the carbon nanodots was accomplished by microwave-assisted co-hydrothermolysis of appropriate precursor compounds. After isolation and purification by dialysis particles in the single-digit nanometer-range were obtained and characterized with regard to their photoluminescence properties in terms of emission wavelength, pH stability, and quantum yield. All types of synthesized CDs reached their PL maxima (450–480 nm; light blue) in a narrow excitation wavelength range of 340–360 nm. Variation of molar (C/N) ratio of the CD precursors and substitution of the nitrogen donor EDEA by urea increased PL and quantum yield (QY), respectively. The highest relative QY of nearly 32% was obtained for CDs synthesized from citric acid and urea. PL of all CDs was virtually insensitive to pH changes in the range of 4–10. Tensile testing of hybrid nanopaper prepared after EDC/NHS-mediated grafting of GEA-type CDs onto TOBC (0.52 mmol·g−1 COOH) in dispersion state revealed that both stiffness and strength are not compromised by incorporation of carbon dots, while plastic deformation and elongation at break increased slightly compared to nanopaper formed prior to decoration with CDs. Water contact angle of the nanopaper is unaffected by introduction of carbon dots which is supposedly due to the presence of surface amino- and amide groups compensating for the loss of carboxyl groups by grafting.


RSC Advances ◽  
2020 ◽  
Vol 10 (25) ◽  
pp. 14979-14990 ◽  
Author(s):  
Mohammed Abdullah Issa ◽  
Zurina Z. Abidin ◽  
Musa Y. Pudza ◽  
Hamid Zentou

Low value waste resources have been converted into value-added luminescence carbon dots for copper adsorption from contaminated water.


2015 ◽  
Vol 51 (100) ◽  
pp. 17768-17771 ◽  
Author(s):  
Juan Hou ◽  
Long Wang ◽  
Ping Zhang ◽  
Yuan Xu ◽  
Lan Ding

A rapid preparative method for carbon dots in an immiscible system was proposed. CDs possess high quantum yield, excitation-independent emission and thermally activated delayed fluorescence.


2021 ◽  
Author(s):  
Wenjing Chen ◽  
Jun Fan ◽  
Xianxue Wu ◽  
Dongbao Hu ◽  
Yunying Wu ◽  
...  

In this work, a facile one-step hydrothermal method was developed to synthesize nitrogen-doped carbon dots (N-CDs) using pork liver. The quantum yield of the prepared N-CDs was as high as...


2021 ◽  
Vol 175 ◽  
pp. 516-525
Author(s):  
Lan Sun ◽  
Zhenye Mo ◽  
Qiong Li ◽  
Dafeng Zheng ◽  
Xueqing Qiu ◽  
...  

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