The Effect of Organic Cation Dynamics on the Optical Properties in (PEA)2(MA)[Pb2I7] Perovskite Dimorphs

2021 ◽  
Author(s):  
Lekina Yulia ◽  
Sai Dintakurti ◽  
Benny Febriansyah ◽  
David George Bradley ◽  
Jiaxu Yan ◽  
...  
Keyword(s):  
Phase Transition ◽  
Optical Properties ◽  
Raman Scattering ◽  
Organic Cation ◽  
Two Dimensional ◽  
Lead Iodide ◽  
Temperature Dependent ◽  
Hybrid Perovskite

Two-dimensional (2D) phenylethyl ammonium (PEA+)-methyl ammonium (MA+) lead iodide ((PEA)2(MA)[Pb2I7]) hybrid perovskite exists as temperature-dependent dimorphs exhibiting an ill-defined phase transition occurring over 150 - 200 K range. Raman scattering,...

Influence of mixed organic cations on the structural and optical properties of lead tri-iodide perovskites

Nanoscale ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 5215-5221 ◽  
Author(s):  
Guotao Pang ◽  
Xiaoqi Lan ◽  
Ruxue Li ◽  
Zhubing He ◽  
Rui Chen
Keyword(s):  
Phase Transition ◽  
Optical Properties ◽  
Organic Cation ◽  
Organic Cations ◽  
Temperature Dependent ◽  
Structural And Optical Properties ◽  
Transition Range ◽  
Phase Transition Range ◽  
Temperature Dependent Photoluminescence

Temperature-dependent photoluminescence in the phase transition range shows that mixed-organic-cation perovskites are more stable than their pure counterparts.

Impact of excess PbI2 on the structure and the temperature dependent optical properties of methylammonium lead iodide perovskites

2018 ◽  
Vol 6 (28) ◽  
pp. 7512-7519 ◽  
Author(s):  
Tobias Meier ◽  
Tanaji P. Gujar ◽  
Andreas Schönleber ◽  
Selina Olthof ◽  
Klaus Meerholz ◽  
...  
Keyword(s):  
Thin Films ◽  
Phase Transition ◽  
Optical Properties ◽  
Electronic Structure ◽  
Binding Energy ◽  
Direct Impact ◽  
Lead Iodide ◽  
Temperature Dependent ◽  
Methylammonium Lead Iodide ◽  
Transition Behaviour

Excess PbI2 in MAPbI3 thin films has no direct impact on the electronic structure but changes the temperature dependence of the exciton binding energy and the phase transition behaviour.

Temperature-dependent photoluminescence properties of mixed-cation methylammonium–formamidium lead iodide [HC(NH2)2]x[CH3NH3]1−xPbI3 perovskite nanostructures

2017 ◽  
Vol 5 (46) ◽  
pp. 12057-12061 ◽  
Author(s):  
Hongge Zheng ◽  
Jun Dai ◽  
Junjie Duan ◽  
Feng Chen ◽  
Gangyi Zhu ◽  
...  
Keyword(s):  
Phase Transition ◽  
Optical Properties ◽  
Transition Temperature ◽  
Tetragonal Phase ◽  
Photoluminescence Properties ◽  
Lead Iodide ◽  
Temperature Dependent ◽  
Urbach Tail ◽  
Tetragonal Phase Transition ◽  
Temperature Dependent Photoluminescence

Orthorhombic–tetragonal phase transition, temperature-dependent PL related optical properties and Urbach tail characteristics are systematically investigated in the FAxMA1−xPbI3 nanostructures.

Anomalous Temperature-Dependent Raman Scattering of Vapor-Deposited Two-Dimensional Bi Thin Films

2018 ◽  
Vol 122 (42) ◽  
pp. 24459-24466 ◽  
Author(s):  
Donglin Lu ◽  
Siwei Luo ◽  
Shuhua Liu ◽  
Hao Yao ◽  
Xiaohui Ren ◽  
...  
Keyword(s):  
Thin Films ◽  
Raman Scattering ◽  
Two Dimensional ◽  
Temperature Dependent ◽  
Anomalous Temperature

scholarly journals Structures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
P. S. Whitfield ◽  
N. Herron ◽  
W. E. Guise ◽  
K. Page ◽  
Y. Q. Cheng ◽  
...  
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Structural Phase ◽  
Photovoltaic Performance ◽  
Orthorhombic Phase ◽  
Structural Phase Transitions ◽  
Lead Iodide ◽  
First Order ◽  
Hybrid Perovskite ◽  
The Impact

Abstract We have examined the crystal structures and structural phase transitions of the deuterated, partially deuterated and hydrogenous organic-inorganic hybrid perovskite methyl ammonium lead iodide (MAPbI3) using time-of-flight neutron and synchrotron X-ray powder diffraction. Near 330 K the high temperature cubic phases transformed to a body-centered tetragonal phase. The variation of the order parameter Q for this transition scaled with temperature T as Q ∼ (Tc−T)β, where Tc is the critical temperature and the exponent β was close to ¼, as predicted for a tricritical phase transition. However, we also observed coexistence of the cubic and tetragonal phases over a range of temperature in all cases, demonstrating that the phase transition was in fact first-order, although still very close to tricritical. Upon cooling further, all the tetragonal phases transformed into a low temperature orthorhombic phase around 160 K, again via a first-order phase transition. Based upon these results, we discuss the impact of the structural phase transitions upon photovoltaic performance of MAPbI3 based solar cells.

Phase transition analysis of thermochromic VO2 thin films by temperature-dependent Raman scattering and ellipsometry

2018 ◽  
Vol 456 ◽  
pp. 545-551 ◽  
Author(s):  
Ying Huang ◽  
Dongping Zhang ◽  
Yi Liu ◽  
Jingcheng Jin ◽  
Yu Yang ◽  
...  
Keyword(s):  
Thin Films ◽  
Phase Transition ◽  
Raman Scattering ◽  
Temperature Dependent ◽  
Transition Analysis ◽  
Vo2 Thin Films

Temperature-dependent phase transition and comparative investigation on enhanced magnetic and optical properties between sillenite and perovskite bismuth ferrite-rGO nanocomposites

2017 ◽  
Vol 122 (8) ◽  
pp. 084902 ◽  
Author(s):  
M. A. Jalil ◽  
Sayeed Shafayet Chowdhury ◽  
Mashnoon Alam Sakib ◽  
S. M. Enamul Hoque Yousuf ◽  
Emran Khan Ashik ◽  
...  
Keyword(s):  
Phase Transition ◽  
Optical Properties ◽  
Bismuth Ferrite ◽  
Comparative Investigation ◽  
Temperature Dependent

Micro-dynamics mechanism of the phase transition behavior of poly(N-isopropylacrylamide-co-2-hydroxyethyl methacrylate) hydrogels revealed by two-dimensional correlation spectroscopy

2017 ◽  
Vol 8 (5) ◽  
pp. 865-878 ◽  
Author(s):  
Gehong Su ◽  
Tao Zhou ◽  
Xifei Liu ◽  
Yanan Ma
Keyword(s):  
Phase Transition ◽  
Ftir Spectroscopy ◽  
Correlation Spectroscopy ◽  
Volume Phase Transition ◽  
Hydroxyethyl Methacrylate ◽  
Two Dimensional ◽  
Phase Transition Behavior ◽  
Temperature Dependent ◽  
Volume Phase ◽  
Transition Behavior

The micro-dynamics mechanism of the volume phase transition of PNIPAM-co-HEMA hydrogels was established using temperature-dependent FTIR spectroscopy, PCMW2D, and 2DCOS analysis.

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