Where is the Best Substitution Position of Amino Groups on Carbon Dots: A Computational Strategy toward Long-Wavelength Red Emission

Author(s):  
Nengjie Cao ◽  
Quan Wang ◽  
Xianggui Zhou ◽  
Yixun Gao ◽  
Yancong Feng ◽  
...  

Carbon dots (CDs) are a promising fluorescent material in biological and optoelectronic applications owing to their high biocompatibility, low cytotoxicity, and high stability. Red emission CDs are not only widely...

2019 ◽  
Vol 11 (20) ◽  
pp. 2626-2629 ◽  
Author(s):  
Shiying Gao ◽  
Yanyan Ma ◽  
Weiying Lin

A deep-red emission fluorescent probe HY for detecting viscosity in living systems was developed. The probe exhibited ideal properties including good selectivity, high stability and low cytotoxicity. Importantly, the probe HY has been successfully utilized for monitoring viscosity variations in cells and living mice.


Author(s):  
Xiao-Qi Yu ◽  
Ping Chen ◽  
Xi He ◽  
Xiao-Li Tian ◽  
Ji Zhang

As a new-type of fluorescent material, carbon dots (CDs) are promising nanoscale reagents with the potential to integrate the functions of bio-imaging and gene / drug delivery. Most of reported...


e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 317-327
Author(s):  
Chenliang Shi ◽  
Ling Lin ◽  
Yukun Yang ◽  
Wenjia Luo ◽  
Maoqing Deng ◽  
...  

AbstractThe influence of density of amino groups, nanoparticles dimension and pH on the interaction between end-functionalized polymers and nanoparticles was extensively investigated in this study. PS–NH2 and H2N–PS–NH2 were prepared using reversible addition–fragmentation chain transfer polymerization and atom transfer radical polymerization. Zero-dimensional carbon dots with sulfonate groups, one-dimensional cellulose nanocrystals with sulfate groups and two-dimensional graphene with sulfonate groups in the aqueous phase were added into the toluene phase containing the aminated PS. The results indicate that aminated PS exhibited the strongest interfacial activity after compounding with sulfonated nanoparticles at a pH of 3. PS ended with two amino groups performed better in reducing the water/toluene interfacial tension than PS ended with only one amino group. The dimension of sulfonated nanoparticles also contributed significantly to the reduction in the water/toluene interfacial tension. The minimal interfacial tension was 4.49 mN/m after compounding PS–NH2 with sulfonated zero-dimensional carbon dots.


Author(s):  
Qiuqi Li ◽  
Dan Cao ◽  
Xueyin Liu ◽  
Xiangyu Zhou ◽  
Xiaoshuang Chen ◽  
...  

A hierarchical computational screening method is used to find layered lead-free metal halide perovskites with high stability and outstanding optoelectronic properties.


RSC Advances ◽  
2017 ◽  
Vol 7 (80) ◽  
pp. 50802-50811 ◽  
Author(s):  
Ya Peng ◽  
Xinyan Zhou ◽  
Nannan Zheng ◽  
Lingyu Wang ◽  
Xingping Zhou

A novel way has been established to make the FCDs with a very high QY, high stability, low cell cytotoxicity, and outstanding performance as a fluorescence probe.


2014 ◽  
Vol 2 (40) ◽  
pp. 7065-7072 ◽  
Author(s):  
Jia-Tao Miao ◽  
Chen Fan ◽  
Ru Sun ◽  
Yu-Jie Xu ◽  
Jian-Feng Ge

A cellular dye with properties of long-wave emission, large Stokes shift, water solubility, low cytotoxicity, and good photostability is reported.


Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2316
Author(s):  
Chao Kang ◽  
Ying Huang ◽  
Hui Yang ◽  
Xiu Fang Yan ◽  
Zeng Ping Chen

The fluorescent carbon dot is a novel type of carbon nanomaterial. In comparison with semiconductor quantum dots and fluorescence organic agents, it possesses significant advantages such as excellent photostability and biocompatibility, low cytotoxicity and easy surface functionalization, which endow it a wide application prospect in fields of bioimaging, chemical sensing, environmental monitoring, disease diagnosis and photocatalysis as well. Biomass waste is a good choice for the production of carbon dots owing to its abundance, wide availability, eco-friendly nature and a source of low cost renewable raw materials such as cellulose, hemicellulose, lignin, carbohydrates and proteins, etc. This paper reviews the main sources of biomass waste, the feasibility and superiority of adopting biomass waste as a carbon source for the synthesis of carbon dots, the synthetic approaches of carbon dots from biomass waste and their applications. The advantages and deficiencies of carbon dots from biomass waste and the major influencing factors on their photoluminescence characteristics are summarized and discussed. The challenges and perspectives in the synthesis of carbon dots from biomass wastes are also briefly outlined.


2016 ◽  
Vol 40 (10) ◽  
pp. 8809-8814 ◽  
Author(s):  
Shasha Xu ◽  
Yingzhong Zhu ◽  
Rui Li ◽  
Jian Su ◽  
Shengli Li ◽  
...  

Two novel D–π–A structural chromophores showing large 2PA active cross-sections, low cytotoxicity and high stability in near-IR bio-imaging.


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