scholarly journals Engineering Donor-Acceptor Conjugated Polymers for High-Performance and Fast-Response Organic Electrochemical Transistors

2021 ◽  
Author(s):  
Hanyu Jia ◽  
Zhen Huang ◽  
Peiyun Li ◽  
Yunfei Wang ◽  
Song Zhang ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
High Performance ◽  
High Mobility ◽  
Fast Response ◽  
Donor Acceptor ◽  
Organic Electrochemical Transistors

To date, high-performance organic electrochemical transistors (OECTs) are mostly based on polythiophene systems. Donor-acceptor (D-A) conjugated polymers are expected to be promising materials for OECTs owing to their high mobility...

scholarly journals Engineering Donor-Acceptor Conjugated Polymers for High-Performance and Fast-Response Organic Electrochemical Transistors

2020 ◽  
Author(s):  
Hanyu Jia ◽  
Zhen Huang ◽  
Peiyun Li ◽  
song zhang ◽  
yunfei wang ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
High Performance ◽  
High Mobility ◽  
Hole Mobility ◽  
Fast Response ◽  
Ion Diffusion ◽  
Order Of Magnitude ◽  
Donor Acceptor ◽  
Systematic Solution ◽  
Organic Electrochemical Transistors

To date, high-performance organic electrochemical transistors (OECTs) are all based on polythiophene systems. Donor-acceptor (D-A) conjugated polymers are expected to be promising materials for OECTs owing to their high mobility and comparatively low crystallinity (good for ion diffusion). However, the OECT performance of D-A polymers lags far behind that of the polythiophenes. Here we synergistically engineered the backbone, side chain of a series of diketopyrrolopyrrole (DPP)-based D-A polymers and found that redox potential, molecular weight, solution processability, and film microstructures are essential to their performance. Among the polymers, P(bgDPP-MeOT2) exhibited a figure-of-merit (μC*) of 225 F cm<sup>–1</sup> V<sup>–1</sup> s<sup>–1</sup>, <a>over one order of magnitude higher than previously reported D-A polymers. Besides, the DPP polymers exhibited high hole mobility over 2 cm<sup>2</sup> V</a><sup>−1</sup> s<sup>−1</sup>, significantly higher than all D-A polymers employed in OECTs, leading to fast response OECTs with a record low turn-off response time of 30 μs. <a>The polymer also exhibited better stability than polythiophene systems with current retention of 98.8% over 700 electrochemical switching cycles.</a> This work provides a systematic solution to unleash the high-performance and fast-response nature of D-A polymers in OECTs.

scholarly journals Engineering Donor-Acceptor Conjugated Polymers for High-Performance and Fast-Response Organic Electrochemical Transistors

2020 ◽  
Author(s):  
Hanyu Jia ◽  
Zhen Huang ◽  
Peiyun Li ◽  
song zhang ◽  
yunfei wang ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
High Performance ◽  
High Mobility ◽  
Hole Mobility ◽  
Fast Response ◽  
Ion Diffusion ◽  
Order Of Magnitude ◽  
Donor Acceptor ◽  
Systematic Solution ◽  
Organic Electrochemical Transistors

To date, high-performance organic electrochemical transistors (OECTs) are all based on polythiophene systems. Donor-acceptor (D-A) conjugated polymers are expected to be promising materials for OECTs owing to their high mobility and comparatively low crystallinity (good for ion diffusion). However, the OECT performance of D-A polymers lags far behind that of the polythiophenes. Here we synergistically engineered the backbone, side chain of a series of diketopyrrolopyrrole (DPP)-based D-A polymers and found that redox potential, molecular weight, solution processability, and film microstructures are essential to their performance. Among the polymers, P(bgDPP-MeOT2) exhibited a figure-of-merit (μC*) of 225 F cm<sup>–1</sup> V<sup>–1</sup> s<sup>–1</sup>, <a>over one order of magnitude higher than previously reported D-A polymers. Besides, the DPP polymers exhibited high hole mobility over 2 cm<sup>2</sup> V</a><sup>−1</sup> s<sup>−1</sup>, significantly higher than all D-A polymers employed in OECTs, leading to fast response OECTs with a record low turn-off response time of 30 μs. <a>The polymer also exhibited better stability than polythiophene systems with current retention of 98.8% over 700 electrochemical switching cycles.</a> This work provides a systematic solution to unleash the high-performance and fast-response nature of D-A polymers in OECTs.

scholarly journals Donor–acceptor stacking arrangements in bulk and thin-film high-mobility conjugated polymers characterized using molecular modelling and MAS and surface-enhanced solid-state NMR spectroscopy

2017 ◽  
Vol 8 (4) ◽  
pp. 3126-3136 ◽  
Author(s):  
Sachin R. Chaudhari ◽  
John M. Griffin ◽  
Katharina Broch ◽  
Anne Lesage ◽  
Vincent Lemaur ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Conjugated Polymers ◽  
Molecular Modelling ◽  
Solid State Nmr ◽  
High Mobility ◽  
Surface Enhanced ◽  
Donor Acceptor

DPP-DTT adopts a donor-on-acceptor stacking arrangement which is preserved in thin films.

Designing Donor–Acceptor Copolymers for Stable and High-Performance Organic Electrochemical Transistors

2021 ◽  
pp. 1061-1067
Author(s):  
Xuyi Luo ◽  
Hongguang Shen ◽  
Kuluni Perera ◽  
Dung Trong Tran ◽  
Bryan W. Boudouris ◽  
...  
Keyword(s):  
High Performance ◽  
Donor Acceptor ◽  
Organic Electrochemical Transistors

Multifluorination toward High-Mobility Ambipolar and Unipolar n-Type Donor-Acceptor Conjugated Polymers Based on Isoindigo

2017 ◽  
Vol 29 (13) ◽  
pp. 1606217 ◽  
Author(s):  
Yao Gao ◽  
Yunfeng Deng ◽  
Hongkun Tian ◽  
Jidong Zhang ◽  
Donghang Yan ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
High Mobility ◽  
Donor Acceptor

Pyrrolophthalazine dione (PPD)-based donor–acceptor polymers as high performance electrochromic materials

2015 ◽  
Vol 6 (9) ◽  
pp. 1487-1494 ◽  
Author(s):  
Qun Ye ◽  
Wei Teng Neo ◽  
Tingting Lin ◽  
Jing Song ◽  
Hong Yan ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
High Performance ◽  
Optical Contrast ◽  
Electrochromic Materials ◽  
Coloration Efficiency ◽  
Term Stability ◽  
Long Term Stability ◽  
Donor Acceptor ◽  
Solution Processable

Novel solution-processable pyrrolophthalazine dione-containing electrochromic conjugated polymers with high optical contrast, high coloration efficiency, and good long-term stability were reported.

scholarly journals Doping High‐Mobility Donor–Acceptor Copolymer Semiconductors with an Organic Salt for High‐Performance Thermoelectric Materials

2020 ◽  
Vol 6 (3) ◽  
pp. 1900945 ◽  
Author(s):  
Jing Guo ◽  
Guodong Li ◽  
Heiko Reith ◽  
Lang Jiang ◽  
Ming Wang ◽  
...  
Keyword(s):  
Thermoelectric Materials ◽  
High Performance ◽  
High Mobility ◽  
Organic Salt ◽  
Donor Acceptor

Ethylenedioxythiophene incorporated diketopyrrolopyrrole conjugated polymers for high-performance organic electrochemical transistors

2021 ◽  
Author(s):  
Naixiang Wang ◽  
Liuping Xie ◽  
Haifeng Ling ◽  
Venkatesh Piradi ◽  
Li Li ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
High Performance ◽  
Biological Applications ◽  
Organic Electrochemical Transistors

The synthesis of conjugated polymers specifically for organic electrochemical transistors (OECTs) has attracted much attention recently for the great potential in biological applications. In this case, not only the carrier...

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