Magnetic field assisted electrocatalytic oxygen evolution reaction of nickel-based materials

2022 ◽  
Author(s):  
Yuanyuan Zhang ◽  
Ping Guo ◽  
Siwei Li ◽  
Jianmin Sun ◽  
Wei Wang ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Oxygen Evolution ◽  
Electron Scattering ◽  
Oxygen Evolution Reaction ◽  
Dominant Role ◽  
Testing System ◽  
Magnetoresistance Effect ◽  
Electrochemical Testing

The dominant role of the magnetoresistance effect caused by spin electron scattering in the oxygen evolution reaction is unveiled through an in situ tunable magnetic field-electrochemical testing system.

scholarly journals Influence of Chemical Operation on the Electrocatalytic Activity of Ba0.5Sr0.5Co0.8Fe0.2O3−δ for the Oxygen Evolution Reaction

2021 ◽  
Author(s):  
Yuta Inoue ◽  
Yuto Miyahara ◽  
Kohei Miyazaki ◽  
Yasuyuki Kondo ◽  
Yuko Yokoyama ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Alkaline Solution ◽  
Oxygen Evolution Reaction ◽  
Time Course ◽  
Potential Cycling ◽  
Leaching Behavior ◽  
Fundamental Understanding ◽  
A Site

Abstract Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) is a promising electrocatalyst for the oxygen evolution reaction (OER) in alkaline solution. The OER activities of BSCF are gradually enhanced by prolonging the duration of electrochemical operation at OER potentials, but the underlying cause is not fully understood. In this study, we investigated the role of chemical operation, equivalent to immersion in alkaline solution, in the time-course of OER enhancement of BSCF. Interestingly, the time-course OER enhancement of BSCF was promoted not only by electrochemical operation, which corresponds to potential cycling in the OER region, but also by chemical operation. In situ Raman measurements clarified that chemical operation had a lower rate of surface amorphization than electrochemical operation. On the other hand, the leaching behavior of A-site cations was comparable between chemical and electrochemical operations. Since the OER activity of BSCF was stabilized by saturating the electrolyte with Ba2+, “chemical” A-site leaching was key to inducing the time-course OER enhancement on perovskite electrocatalysts. Based on these results, we provide a fundamental understanding of the role of chemical operation in the OER properties of perovskites.

MOF-derived M-OOH with rich oxygen defects by in-situ electro-oxidation reconstitution for highly efficient oxygen evolution reaction

2021 ◽  
Author(s):  
Zhikai Shi ◽  
Zebin Yu ◽  
Ronghua Jiang ◽  
Jun Huang ◽  
Yanping Hou ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Energy Production ◽  
Low Cost ◽  
Highly Efficient ◽  
Oxygen Defects ◽  
Electro Oxidation

The oxygen evolution reaction (OER) is an important half-reaction in the field of energy production. However, how effectively, simply, and greenly to prepare low-cost OER electrocatalysts remains a problem. Herein,...

The electron-transfer intermediates of the oxygen evolution reaction (OER) as polarons by in situ spectroscopy

2021 ◽  
Author(s):  
Hanna Lyle ◽  
Suryansh Singh ◽  
Michael Paolino ◽  
Ilya Vinogradov ◽  
Tanja Cuk
Keyword(s):  
Electron Transfer ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Catalytic Reactions ◽  
In Situ Spectroscopy ◽  
Chemical Bonds

The conversion of diffusive forms of energy (electrical and light) into short, compact chemical bonds by catalytic reactions regularly involves moving a carrier from an environment that favors delocalization to one that favors localization.

In-situ coating amorphous boride on ternary pyrite-type boron sulfide for highly efficient oxygen evolution

2021 ◽  
Author(s):  
Tingting Li ◽  
Tianyun Jing ◽  
Dewei Rao ◽  
Xiaotian Jia ◽  
Yunpeng Zuo ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Highly Efficient ◽  
In Situ Coating ◽  
Electrochemical Oxygen

Multimetallic pyrite-type sulfides have been a promising electrocatalytic materials for electrochemical oxygen evolution reaction (OER), but still requires further improve due to the easily oxidization of surface atoms and the...

Revealing the structural transformation of rutile RuO2via in situ X-ray absorption spectroscopy during the oxygen evolution reaction

2019 ◽  
Vol 48 (21) ◽  
pp. 7122-7129 ◽  
Author(s):  
Chia-Jui Chang ◽  
You-Chiuan Chu ◽  
Hao-Yu Yan ◽  
Yen-Fa Liao ◽  
Hao Ming Chen
Keyword(s):  
Oxygen Evolution ◽  
Structural Transformation ◽  
Absorption Spectroscopy ◽  
Oxygen Evolution Reaction ◽  
The State ◽  
X Ray ◽  
Alkaline Conditions ◽  
X Ray Absorption ◽  
State Of Art

The state-of-art RuO2 catalyst for the oxygen evolution reaction (OER) is measured by using in situ X-ray absorption spectroscopy (XAS) to elucidate the structural transformation during catalyzing the reaction in acidic and alkaline conditions.

In situ growth of ultrathin Ni–Fe LDH nanosheets for high performance oxygen evolution reaction

2017 ◽  
Vol 4 (7) ◽  
pp. 1173-1181 ◽  
Author(s):  
Haidong Yang ◽  
Sha Luo ◽  
Yun Bao ◽  
Yutong Luo ◽  
Jun Jin ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Copper Foil ◽  
Catalytic Performance ◽  
In Situ Growth ◽  
Ultrathin Nanosheet

The ultrathin Ni70Fe30LDH nanosheets were successfullyin situgrown on anodic polarized copper foil, denoted as u-Ni70Fe30LDHs/a-CF. Benefiting from the ultrathin nanosheet structure, the catalyst exhibits remarkable catalytic performance for OER in 1 M KOH solution.

In situ decoration of stainless steel nanoparticles for synergistic enhancement of α-Ni(OH)2 oxygen evolution reaction catalysis

2017 ◽  
Vol 1 (11) ◽  
pp. 2376-2382 ◽  
Author(s):  
Anirudh Balram ◽  
Hanfei Zhang ◽  
Sunand Santhanagopalan
Keyword(s):  
Stainless Steel ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Synergistic Enhancement ◽  
Enhanced Activity

This work reports inexpensive stainless steel support enhanced activity of α-Ni(OH)2 for high performance OER catalysis.

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