In-situ gelation regulating micro-electric fields to induced Li deposition in quasi-solid-state lithium metal batteries

2022 ◽  
Author(s):  
Qiyu Wang ◽  
Xiang-Qun Xu ◽  
Bo Hong ◽  
Maohui Bai ◽  
Jie Li ◽  
...  
Keyword(s):  
Solid State ◽  
Electric Fields ◽  
Energy System ◽  
High Energy ◽  
Energy Capacity ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
In Situ Gelation ◽  
Lithium Metal Battery

Quasi-solid-state lithium metal battery has great potential in next generation energy system for its high energy capacity and security. However, the system still suffers from incompatible interphases and limited cycling...

scholarly journals Upgrading traditional liquid electrolyte via in situ gelation for future lithium metal batteries

2018 ◽  
Vol 4 (10) ◽  
pp. eaat5383 ◽  
Author(s):  
Feng-Quan Liu ◽  
Wen-Peng Wang ◽  
Ya-Xia Yin ◽  
Shuai-Feng Zhang ◽  
Ji-Lei Shi ◽  
...  
Keyword(s):  
Large Scale ◽  
Gel Polymer Electrolyte ◽  
High Energy ◽  
Liquid Electrolyte ◽  
Protective Effects ◽  
Lithium Metal ◽  
Electrolyte System ◽  
Lithium Metal Batteries ◽  
In Situ Gelation

High-energy lithium metal batteries (LMBs) are expected to play important roles in the next-generation energy storage systems. However, the uncontrolled Li dendrite growth in liquid electrolytes still impedes LMBs from authentic commercialization. Upgrading the traditional electrolyte system from liquid to solid and quasi-solid has therefore become a key issue for prospective LMBs. From this premise, it is particularly urgent to exploit facile strategies to accomplish this goal. We report that commercialized liquid electrolyte can be easily converted into a novel quasi-solid gel polymer electrolyte (GPE) via a simple and efficient in situ gelation strategy, which, in essence, is to use LiPF6 to induce the cationic polymerization of the ether-based 1,3-dioxolane and 1,2-dimethoxyethane liquid electrolyte under ambient temperature. The newly developed GPE exhibits elevated protective effects on Li anodes and has universality for diversified cathodes including but not restricted to sulfur, olivine-type LiFePO4, and layered LiNi0.6Co0.2Mn0.2O2, revealing tremendous potential in promoting the large-scale application of future LMBs.

An in Situ-Formed High Lithiophilic Solid Lubricant Interface Layer for Garnet-Based Solid-State Lithium Metal Batteries

2021 ◽  
pp. 139767
Author(s):  
Guiye Yang ◽  
Yu Zhang ◽  
Zhikun Guo ◽  
Chenyang Zhao ◽  
Xiaoming Bai ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Lubricant ◽  
Interface Layer ◽  
Lithium Metal ◽  
Lithium Metal Batteries

An Investigation of Chemo-Mechanical Phenomena in All-Solid-State Lithium Metal Batteries Using in-Situ Curvature Measurements

2021 ◽  
Vol MA2021-02 (3) ◽  
pp. 365-365
Author(s):  
Jung Hwi Cho ◽  
Kun Joong Kim ◽  
Srinath Chakravarthy ◽  
Xingcheng Xiao ◽  
Jennifer L.M. Rupp ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Curvature Measurements ◽  
Mechanical Phenomena

In situ thermally polymerized solid composite electrolytes with a broad electrochemical window for all-solid-state lithium metal batteries

2020 ◽  
Vol 8 (7) ◽  
pp. 3892-3900 ◽  
Author(s):  
Zhuo Li ◽  
Hui-Xin Xie ◽  
Xing-Yan Zhang ◽  
Xin Guo
Keyword(s):  
Solid State ◽  
High Performance ◽  
Lithium Metal ◽  
Composite Electrolytes ◽  
Lithium Metal Batteries ◽  
Electrochemical Window ◽  
Li Batteries

In situ polymerization creates composite electrolytes with broad electrochemical windows and conformal interfaces with electrodes, resulting in high-performance solid-state NCM-Li batteries.

High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes

Nature Energy ◽  
2020 ◽  
Vol 5 (4) ◽  
pp. 299-308 ◽  
Author(s):  
Yong-Gun Lee ◽  
Satoshi Fujiki ◽  
Changhoon Jung ◽  
Naoki Suzuki ◽  
Nobuyoshi Yashiro ◽  
...  
Keyword(s):  
Solid State ◽  
High Energy ◽  
Carbon Composite ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Composite Anodes

In-situ visualization of lithium plating in all-solid-state lithium-metal battery

Nano Energy ◽  
2019 ◽  
Vol 63 ◽  
pp. 103895 ◽  
Author(s):  
Quan Li ◽  
Tiancheng Yi ◽  
Xuelong Wang ◽  
Hongyi Pan ◽  
Baogang Quan ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Metal ◽  
In Situ Visualization ◽  
Lithium Metal Battery

scholarly journals Publisher Correction: High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes

Nature Energy ◽  
2020 ◽  
Vol 5 (4) ◽  
pp. 348-348 ◽  
Author(s):  
Yong-Gun Lee ◽  
Satoshi Fujiki ◽  
Changhoon Jung ◽  
Naoki Suzuki ◽  
Nobuyoshi Yashiro ◽  
...  
Keyword(s):  
Solid State ◽  
High Energy ◽  
Carbon Composite ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Composite Anodes
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