Janus behaviour of LiFSI- and LiPF6-based electrolytes for Li metal batteries: chemical corrosion versus galvanic corrosion

Author(s):  
Bomee Kwon ◽  
Jeonghyeop Lee ◽  
Hyunchul Kim ◽  
Dong-min Kim ◽  
Kyobin Park ◽  
...  

Li metal has been considered a promising anode for high energy density Li batteries because of the lowest redox potential and high specific capacity of the Li/Li+ redox couple. However,...

2016 ◽  
Vol 52 (97) ◽  
pp. 14039-14042 ◽  
Author(s):  
Alejandro N. Colli ◽  
Pekka Peljo ◽  
Hubert H. Girault

The MnO4−/MnO42− redox couple has a positive redox potential, high electrochemical reversibility and high solubility, up to 3.62 M at room temperature.


Author(s):  
Wei Hong ◽  
Yawen Li ◽  
Yiru Wu ◽  
Guifang Li ◽  
Lishan Jia

The fine Co3O4 particles derived from ZIF-67 induced self-assembly of NiNH to form sandwich layered Co3O4/NiNH with oxygen vacancies which showed high specific capacity. A Co3O4/NiNH//AC supercapacitor has high energy density and cycle stability.


Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3586
Author(s):  
Qi An ◽  
Xingru Zhao ◽  
Shuangfu Suo ◽  
Yuzhu Bai

Lithium-ion capacitors (LICs) have been widely explored for energy storage. Nevertheless, achieving good energy density, satisfactory power density, and stable cycle life is still challenging. For this study, we fabricated a novel LIC with a NiO-rGO composite as a negative material and commercial activated carbon (AC) as a positive material for energy storage. The NiO-rGO//AC system utilizes NiO nanoparticles uniformly distributed in rGO to achieve a high specific capacity (with a current density of 0.5 A g−1 and a charge capacity of 945.8 mA h g−1) and uses AC to provide a large specific surface area and adjustable pore structure, thereby achieving excellent electrochemical performance. In detail, the NiO-rGO//AC system (with a mass ratio of 1:3) can achieve a high energy density (98.15 W h kg−1), a high power density (10.94 kW kg−1), and a long cycle life (with 72.1% capacity retention after 10,000 cycles). This study outlines a new option for the manufacture of LIC devices that feature both high energy and high power densities.


2021 ◽  
Author(s):  
Zhikang Wang ◽  
Guiqiang Cao ◽  
Da Bi ◽  
Tian-Xiong Tan ◽  
Qingxue Lai ◽  
...  

Lithium-Sulfur batteries have been regarded as the most promising electrochemical energy storage device in consideration of their satisfactory high specific capacity and high energy density. However, the inferior conversion efficiency...


2021 ◽  
Vol 3 (1) ◽  
Author(s):  
Hiroki Takagi ◽  
Koichi Kakimoto ◽  
Daisuke Mori ◽  
Sou Taminato ◽  
Yasuo Takeda ◽  
...  

The demand for high energy density rechargeable batteries beyond lithium-ion batteries has increased for electric vehicles. In the present study, a novel high energy density rechargeable aqueous lithium battery was proposed. The battery was composed of a lithium metal anode, a lithium-stable non-aqueous electrolyte, a water-stable lithium-ion conducting solid electrolyte of Li1.4Al0.4Ge0.2Ti1.4(PO4)3-epoxy-TiO2 separator, and a hydroquinone sulfonic acid (HQS)/benzoquinone sulfonic acid (BQS) redox couple in an aqueous acetic acid solution (HAc). An open-circuit voltage of 3.7 V at 25 °C was recorded, and the theoretical energy density of the battery based on the reaction 2Li + BQS + 2H2O = 2 LiOH + HQS was 833 Whkg-1, about two times higher than that of the lithium-ion battery. The battery was successfully cycled at 0.5 mA cm-2 and 25 °C with low polarization.


2018 ◽  
Vol 42 (9) ◽  
pp. 7043-7048 ◽  
Author(s):  
Yun Deng ◽  
Aifei Xu ◽  
Wangting Lu ◽  
Yanhua Yu ◽  
Cheng Fu ◽  
...  

Graphene-ordered mesoporous carbon hybrids exhibited advanced specific capacity, high energy density and power density, and long cycle life.


2019 ◽  
Vol 40 (4) ◽  
pp. 040401
Author(s):  
Liping Wang ◽  
Cheng Jiang ◽  
Xiaobin Niu

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