Chemical Switch Enabled Autonomous Two-Stage Crosslinking Polymeric Binder for High Performance Silicon Anodes

2021 ◽  
Author(s):  
Zhangxing Shi ◽  
Qian Liu ◽  
Zhenzhen Yang ◽  
Lily A Robertson ◽  
Sambasiva R. Bheemireddy ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
High Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Polymeric Binder ◽  
Silicon Anodes ◽  
Si Anodes

Silicon (Si) is a promising high-capacity anode material for high-energy-density lithium-ion batteries. However, the drastic volumetric changes of Si upon lithiation/delithiation hinder the practical use of Si anodes. Although adhesive...

scholarly journals Enhanced Roles of Carbon Architectures in High-Performance Lithium-Ion Batteries

2019 ◽  
Vol 11 (1) ◽  
Author(s):  
Lu Wang ◽  
Junwei Han ◽  
Debin Kong ◽  
Ying Tao ◽  
Quan-Hong Yang
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
High Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
High Mass

Abstract Lithium-ion batteries (LIBs), which are high-energy-density and low-safety-risk secondary batteries, are underpinned to the rise in electrochemical energy storage devices that satisfy the urgent demands of the global energy storage market. With the aim of achieving high energy density and fast-charging performance, the exploitation of simple and low-cost approaches for the production of high capacity, high density, high mass loading, and kinetically ion-accessible electrodes that maximize charge storage and transport in LIBs, is a critical need. Toward the construction of high-performance electrodes, carbons are promisingly used in the enhanced roles of active materials, electrochemical reaction frameworks for high-capacity noncarbons, and lightweight current collectors. Here, we review recent advances in the carbon engineering of electrodes for excellent electrochemical performance and structural stability, which is enabled by assembled carbon architectures that guarantee sufficient charge delivery and volume fluctuation buffering inside the electrode during cycling. Some specific feasible assembly methods, synergism between structural design components of carbon assemblies, and electrochemical performance enhancement are highlighted. The precise design of carbon cages by the assembly of graphene units is potentially useful for the controlled preparation of high-capacity carbon-caged noncarbon anodes with volumetric capacities over 2100 mAh cm−3. Finally, insights are given on the prospects and challenges for designing carbon architectures for practical LIBs that simultaneously provide high energy densities (both gravimetric and volumetric) and high rate performance.

High energy density amorphous silicon anodes for lithium ion batteries deposited by DC sputtering

2015 ◽  
Vol 293 ◽  
pp. 301-305 ◽  
Author(s):  
Filippos Farmakis ◽  
Costas Elmasides ◽  
Patrik Fanz ◽  
Markus Hagen ◽  
Nikolaos Georgoulas
Keyword(s):  
Energy Density ◽  
Amorphous Silicon ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Silicon Anodes ◽  
Dc Sputtering

scholarly journals Facile Synthesis of FeS@C Particles Toward High-Performance Anodes for Lithium-Ion Batteries

Nanomaterials ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1467
Author(s):  
Xuanni Lin ◽  
Zhuoyi Yang ◽  
Anru Guo ◽  
Dong Liu
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
High Current Density ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Hierarchical Porous

High energy density batteries with high performance are significantly important for intelligent electrical vehicular systems. Iron sulfurs are recognized as one of the most promising anodes for high energy density lithium-ion batteries because of their high theoretical specific capacity and relatively stable electrochemical performance. However, their large-scale commercialized application for lithium-ion batteries are plagued by high-cost and complicated preparation methods. Here, we report a simple and cost-effective method for the scalable synthesis of nanoconfined FeS in porous carbon (defined as FeS@C) as anodes by direct pyrolysis of an iron(III) p-toluenesulfonate precursor. The carbon architecture embedded with FeS nanoparticles provides a rapid electron transport property, and its hierarchical porous structure effectively enhances the ion transport rate, thereby leading to a good electrochemical performance. The resultant FeS@C anodes exhibit high reversible capacity and long cycle life up to 500 cycles at high current density. This work provides a simple strategy for the mass production of FeS@C particles, which represents a critical step forward toward practical applications of iron sulfurs anodes.

scholarly journals Porous Co2VO4 Nanodisk as a High-Energy and Fast-Charging Anode for Lithium-Ion Batteries

2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Jinghui Ren ◽  
Zhenyu Wang ◽  
Peng Xu ◽  
Cong Wang ◽  
Fei Gao ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
High Capacity ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
High Energy ◽  
High Specific Surface Area ◽  
High Energy Density ◽  
Safety Issues ◽  
Fast Charging

AbstractHigh-energy–density lithium-ion batteries (LIBs) that can be safely fast-charged are desirable for electric vehicles. However, sub-optimal lithiation potential and low capacity of commonly used LIBs anode cause safety issues and low energy density. Here we hypothesize that a cobalt vanadate oxide, Co2VO4, can be attractive anode material for fast-charging LIBs due to its high capacity (~ 1000 mAh g−1) and safe lithiation potential (~ 0.65 V vs. Li+/Li). The Li+ diffusion coefficient of Co2VO4 is evaluated by theoretical calculation to be as high as 3.15 × 10–10 cm2 s−1, proving Co2VO4 a promising anode in fast-charging LIBs. A hexagonal porous Co2VO4 nanodisk (PCVO ND) structure is designed accordingly, featuring a high specific surface area of 74.57 m2 g−1 and numerous pores with a pore size of 14 nm. This unique structure succeeds in enhancing Li+ and electron transfer, leading to superior fast-charging performance than current commercial anodes. As a result, the PCVO ND shows a high initial reversible capacity of 911.0 mAh g−1 at 0.4 C, excellent fast-charging capacity (344.3 mAh g−1 at 10 C for 1000 cycles), outstanding long-term cycling stability (only 0.024% capacity loss per cycle at 10 C for 1000 cycles), confirming the commercial feasibility of PCVO ND in fast-charging LIBs.

scholarly journals Self-reductive synthesis of MXene/Na0.55Mn1.4Ti0.6O4hybrids for high-performance symmetric lithium ion batteries

2019 ◽  
Vol 7 (13) ◽  
pp. 7516-7525 ◽  
Author(s):  
Guodong Zou ◽  
Bingcheng Ge ◽  
Hao Zhang ◽  
Qingrui Zhang ◽  
Carlos Fernandez ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Reduction Method ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Bifunctional Properties

A new MXene/Na0.55Mn1.4Ti0.6O4hybrid with bifunctional properties is synthesized by a self-reduction method, providing a high energy density for symmetric LIBs.

Synthesis of Sn–Co@PMMA nanowire arrays by electrodeposition and in situ polymerization as a high performance lithium-ion battery anode

RSC Advances ◽  
2015 ◽  
Vol 5 (116) ◽  
pp. 95488-95494 ◽  
Author(s):  
Haowen Meng ◽  
Hongyan Yang ◽  
Xiaohui Yu ◽  
Peng Dou ◽  
Daqian Ma ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
In Situ Polymerization ◽  
Lithium Ion ◽  
High Energy ◽  
Nanowire Arrays ◽  
High Energy Density ◽  
Battery Anode

Transition metals have attracted much attention due to their high energy density in lithium-ion batteries (LIBs).

Olivine LiMnxFe1-xPO4 Cathode Materials for Lithium Ion Batteries: Restricted Factors of Rate Performances

2021 ◽  
Author(s):  
Li Yang ◽  
Wentao Deng ◽  
Wei Xu ◽  
Ye Tian ◽  
Anni Wang ◽  
...  
Keyword(s):  
Energy Density ◽  
Cathode Material ◽  
Lithium Ion Batteries ◽  
Cathode Materials ◽  
High Performance ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density

As a promising cathode material for high performance lithium ion batteries, olivine LiMnxFe1-xPO4 (LMFP) combines the high safety of LiFePO4 and the high energy density of LiMnPO4. However, there are...

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