Refining active sites and hydrogen spillover for boosting visible-light-driven ammonia synthesis at room temperature

2021 ◽  
Author(s):  
Rong Fu ◽  
Ziye Pan ◽  
Xiaowei Mu ◽  
Jiayang Li ◽  
Qingyun Zhan ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Active Sites ◽  
Room Temperature ◽  
Ammonia Synthesis ◽  
Pt Nanoparticles ◽  
Hydrogen Spillover ◽  
Light Irradiation ◽  
Visible Light Driven

Efficient ammonia synthesis was achieved by Mo, Pt modified TiO2−x under visible light irradiation. Pt nanoparticles trigger hydrogen spillover from Pt to Mo, enabling facile NH3 assembly and desorption, as well as increasing free Mo active sites.

Metal free visible light driven oxidation of alcohols to carbonyl derivatives using 3,6-di(pyridin-2-yl)-1,2,4,5-tetrazine (pytz) as catalyst

RSC Advances ◽  
2015 ◽  
Vol 5 (102) ◽  
pp. 84328-84333 ◽  
Author(s):  
Suvendu Samanta ◽  
Papu Biswas
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Light Irradiation ◽  
Metal Free ◽  
Carbonyl Derivatives ◽  
Oxidation Of Alcohols ◽  
Visible Light Driven ◽  
High Yields

A metal-free transformation of alcohols to the corresponding carbonyls in high yields under visible-light irradiation has been achieved at room temperature using di(pyridin-2-yl)-1,2,4,5-tetrazine (pytz) as catalyst.

scholarly journals Effective Photocatalytic Hydrogen Evolution Using Covalent Triazine Framework-Derived Carbon Nitride Nanofiber Containing Carbon Vacancies for Visible-Light-Driven

2021 ◽  
Vol 11 (16) ◽  
pp. 7222
Author(s):  
Liangjing Zhang ◽  
Aiwu Wang ◽  
Mei Zhang ◽  
Zhengyuan Jin ◽  
Huan Yi ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Active Sites ◽  
Carbon Nitride ◽  
Light Irradiation ◽  
H2 Evolution ◽  
Photoexcited Electron ◽  
Energy And Environment ◽  
Visible Light Driven ◽  
Covalent Triazine Framework

In this study, a novel fibrous carbon nitride (FCN) was prepared from laminated covalent triazine framework (CTF) via pyrolysis, using functionalized 2,5-thiophenedicarboxylic acid and melamine as the precursors. A carbon vacancy was produced by two-step calcination in argon and air atmospheres. These carbon vacancies further exposed the edges and diffusion channels of the FCN nanofibers, which accelerated photogenerated charge transfer and provided more active sites. The FCN was characterized using various techniques and used for H2 evolution under visible-light irradiation. The as-synthesized FCN exhibited excellent stability, and its photocatalytic activity for H2 evolution under visible-light irradiation was 66 times higher than that of bare C3N4 (BCN), attaining a maximum H2 evolution rate of 102.63 μmol in 6 h. The FCN remained stable following visible-light irradiation at the end of 10 cycles. The FCN benefited from the absorption of solar energy and a large number of active sites. These advantages facilitated the efficient separation of photoexcited electron-hole pairs to hinder charge recombination. This work generates new insights into the preparation of highly effective FCN photocatalysts that may be put to various applications, especially in the fields of energy and environment.

scholarly journals g-C3N4/γ-Fe2O3/TiO2/Pd: a new magnetically separable photocatalyst for visible-light-driven fluoride-free Hiyama and Suzuki–Miyaura cross-coupling reactions at room temperature

2020 ◽  
Vol 44 (27) ◽  
pp. 11513-11526 ◽  
Author(s):  
Roya Jahanshahi ◽  
Asma Khazaee ◽  
Sara Sobhani ◽  
José Miguel Sansano
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Cross Coupling ◽  
Light Irradiation ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Visible Light Driven ◽  
Magnetically Separable

g-C3N4/γ-Fe2O3/TiO2/Pd is developed as a new magnetically separable photocatalyst for efficient fluoride-free Hiyama and Suzuki–Miyaura cross-coupling reactions at room temperature under visible light irradiation.

In2S3/BiOI composites boost visible-light photocatalytic degradation of tetracycline hydrochloride

CrystEngComm ◽  
2021 ◽  
Author(s):  
Panbing Hu ◽  
Yanmei Xin ◽  
Congfei Yao ◽  
Yuqing Miao
Keyword(s):  
Visible Light ◽  
Photocatalytic Degradation ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Light Irradiation ◽  
Tetracycline Hydrochloride ◽  
Structure And Morphology ◽  
Morphology Characterization ◽  
Visible Light Photocatalytic

The In2S3/BiOI composites were synthesized at room temperature which significantly improved the photocatalytic degradation performance of tetracycline hydrochloride (TC) under visible light irradiation. Structure and morphology characterization have been performed...

Visible light-driven novel g-C3N4/NiFe-LDH composite photocatalyst with enhanced photocatalytic activity towards water oxidation and reduction reaction

2015 ◽  
Vol 3 (36) ◽  
pp. 18622-18635 ◽  
Author(s):  
Susanginee Nayak ◽  
Lagnamayee Mohapatra ◽  
Kulamani Parida
Keyword(s):  
Photocatalytic Activity ◽  
Composite Materials ◽  
Visible Light ◽  
Water Splitting ◽  
Visible Light Irradiation ◽  
Water Oxidation ◽  
Reduction Reaction ◽  
Light Irradiation ◽  
Composite Photocatalyst ◽  
Visible Light Driven

Dispersion of exfoliated CN over the surface of exfoliated LDH composite materials, and its photocatalytic water splitting under visible-light irradiation.

Study on formaldehyde gas-sensing of In2O3-sensitized ZnO nanoflowers under visible light irradiation at room temperature

2012 ◽  
Vol 22 (25) ◽  
pp. 12915 ◽  
Author(s):  
Lina Han ◽  
Dejun Wang ◽  
Jiabao Cui ◽  
Liping Chen ◽  
Tengfei Jiang ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Gas Sensing ◽  
Light Irradiation

Solvothermal synthesis and visible light-driven photocatalytic degradation for tetracycline of Fe-doped SrTiO3

RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47615-47624 ◽  
Author(s):  
Ping Li ◽  
Chunbo Liu ◽  
Guoling Wu ◽  
Yang Heng ◽  
Shuang Lin ◽  
...  
Keyword(s):  
Visible Light ◽  
Photocatalytic Degradation ◽  
Visible Light Irradiation ◽  
Solvothermal Synthesis ◽  
Solvothermal Method ◽  
Light Irradiation ◽  
Photocatalytic Activities ◽  
Visible Light Driven ◽  
Facile Solvothermal Method

In this paper, Fe-doped SrTiO3 (FSTO) photocatalysts were successfully prepared via a facile solvothermal method, and their photocatalytic activities for degrading tetracycline (TC) under visible light irradiation were examined.

Dehydrogenative 6π Heterocyclization under Visible Light Irradiation and Mechanistic Insights

2021 ◽  
Author(s):  
Zhao Zhang ◽  
Haohua Chen ◽  
Niklas Keller ◽  
Qin Xiong ◽  
Lei Liu ◽  
...  
Keyword(s):  
Transition Metals ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Reaction Proceeds ◽  
Visible Light Driven

A visible-light-driven oxidative 6π heterocycilization for the synthesis of structurally diverse π-conjugated polycyclic 1-aminoisoquinolines has been developed. The reaction proceeds under visible-light or sunshine, obviates photocatalyst and transition-metals, and features...

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