Ultra-highly active Ir-Ru-B/CeO2 catalyst for hydrogen generation from hydrazine monohydrate

Author(s):  
Yu-Ping Qiu ◽  
Weizhen Wang ◽  
Mu-Hua Chen ◽  
Qing Shi ◽  
Zhiqing Yang ◽  
...  

On-demand hydrogen generation from catalytic decomposition of hydrazine monohydrate (N2H4·H2O) represents a promising chemical hydrogen storage technology for onboard and portable applications. But the performances of existing catalysts are still...

Author(s):  
Samikannu Prabu ◽  
Kung-Yuh Chiang

The novel and cost-effective highly magnetic nanoparticle (NP) catalysts for hydrazine monohydrate dehydrogenation were successfully developed. It will provide a high gravimetric hydrogen storage capacity.


RSC Advances ◽  
2016 ◽  
Vol 6 (91) ◽  
pp. 88846-88850 ◽  
Author(s):  
Lisi Xie ◽  
Kunyang Wang ◽  
Gu Du ◽  
Abdullah M. Asiri ◽  
Xuping Sun

A 3D hierarchical CuO/Co3O4 core–shell nanowire array works as a robust and highly active catalyst toward the hydrolytic dehydrogenation of NaBH4 for on-demand hydrogen generation in alkaline solutions.


2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Zhang-Hui Lu ◽  
Qilu Yao ◽  
Zhujun Zhang ◽  
Yuwen Yang ◽  
Xiangshu Chen

Ammonia borane (denoted as AB, NH3BH3) and hydrazine borane (denoted as HB, N2H4BH3), having hydrogen content as high as 19.6 wt% and 15.4 wt%, respectively, have been considered as promising hydrogen storage materials. Particularly, the AB and HB hydrolytic dehydrogenation system can ideally release 7.8 wt% and 12.2 wt% hydrogen of the starting materials, respectively, showing their high potential for chemical hydrogen storage. A variety of nanocatalysts have been prepared for catalytic dehydrogenation from aqueous or methanolic solution of AB and HB. In this review, we survey the research progresses in nanocatalysts for hydrogen generation from the hydrolysis or methanolysis of NH3BH3and N2H4BH3.


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