Recent progress in water-splitting and supercapacitor electrode materials based on MOF-derived sulfides

2021 ◽  
Author(s):  
Matheus Ireno da Silva ◽  
Ítalo R. Machadoa ◽  
Henrique E. Toma ◽  
Koiti Araki ◽  
Lúcio Angnes ◽  
...  
Keyword(s):  
Recent Progress ◽  
Electrode Materials ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Energy Storage And Conversion ◽  
Supercapacitor Electrode ◽  
Conversion Materials ◽  
Metal Organic ◽  
Supercapacitor Electrode Materials

Metal–organic frameworks (MOFs) are being extensively reported as ideal templates or precursors for energy storage and conversion materials thanks to their unique architectures with high surface area, high ordered porosity,...

scholarly journals Electrochemical performance of composite electrodes based on rGO, Mn/Cu metal–organic frameworks, and PANI

2022 ◽  
Vol 12 (1) ◽  
Author(s):  
Quoc Bao Le ◽  
Thanh-Huong Nguyen ◽  
Haojie Fei ◽  
Constantin Bubulinca ◽  
Lukas Munster ◽  
...  
Keyword(s):  
Electrode Materials ◽  
Metal Organic Frameworks ◽  
Electrochemical Analysis ◽  
Composite Electrodes ◽  
Supercapacitor Electrode ◽  
Pani Composite ◽  
The Matrix ◽  
Metal Organic ◽  
Electrochemical Double Layer ◽  
Supercapacitor Electrode Materials

AbstractBenzendicarboxylic acid (BDC)-based metal–organic frameworks (MOFs) have been widely utilized in various applications, including supercapacitor electrode materials. Manganese and copper have solid diamond frames formed with BDC linkers among transition metals chosen for MOF formation. They have shown the possibility to enlarge capacitance at different combinations of MOFs and polyaniline (PANI). Herein, reduced graphene oxide (rGO) was used as the matrix to fabricate electrochemical double-layer SCs. PANI and Mn/Cu-MOF's effect on the properties of electrode materials was investigated through electrochemical analysis. As a result, the highest specific capacitance of about 276 F/g at a current density of 0.5 A/g was obtained for rGO/Cu-MOF@PANI composite.

Preparation and Electrochemical Analysis of Ni-Based Metal Organic Frameworks Containing Binary Ligands for Capacitor Electrodes

2021 ◽  
Vol 21 (9) ◽  
pp. 4670-4674
Author(s):  
Hye-Jin Oh ◽  
Yongju Jung ◽  
Seok Kim
Keyword(s):  
Electrode Materials ◽  
Metal Organic Frameworks ◽  
Electrochemical Analysis ◽  
Supercapacitor Electrode ◽  
Trimesic Acid ◽  
Surface Areas ◽  
Electrode Cell ◽  
Metal Organic ◽  
Supercapacitor Electrode Materials ◽  
Charge Discharge

As one of the energy storage systems, supercapacitors have quite long charge-discharge cycle life. Among many kinds of electrode materials, metal organic frameworks (MOFs) have unique properties such as high specific surface areas and large pore volume as supercapacitor electrode materials. Nickel-MOFs consist of binary ligand such as 1,3,5-Trimesic acid (H3BTC) and terephthalic acid (TPA) were used as working electrode materials in three electrode cell for capacitor system. When synthesizing MOFs, it is possible to prepare uniform crystals using hydrothermal synthesis. The morphology of composites was analyzed by field emission scanning electron microscopy (FE-SEM). Electrochemical properties were measured by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) in 6M KOH electrolyte.

scholarly journals Novel binder-free electrode materials for supercapacitors utilizing high surface area carbon nanofibers derived from immiscible polymer blends of PBI/6FDA-DAM:DABA

RSC Advances ◽  
2017 ◽  
Vol 7 (34) ◽  
pp. 20947-20959 ◽  
Author(s):  
Nimali C. Abeykoon ◽  
Velia Garcia ◽  
Rangana A. Jayawickramage ◽  
Wijayantha Perera ◽  
Jeremy Cure ◽  
...  
Keyword(s):  
Electrode Materials ◽  
High Surface ◽  
High Surface Area ◽  
Electrospun Fibers ◽  
Supercapacitor Electrode ◽  
Immiscible Polymer Blends ◽  
High Performing ◽  
Immiscible Blends ◽  
Binder Free ◽  
Supercapacitor Electrode Materials

High performing supercapacitor electrode materials were obtained by controlling the nanostructure of electrospun fibers derived from PBI/6FDD immiscible blends.

scholarly journals Topological properties of metal-organic frameworks

2020 ◽  
Vol 43 (1) ◽  
pp. 67-76 ◽  
Author(s):  
Hafiz Muhammad Awais ◽  
Muhammad Jamal ◽  
Muhammad Javaid
Keyword(s):  
Electrode Materials ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
Molecular Graph ◽  
High Surface Area ◽  
Organic Ligands ◽  
Energy Storage Devices ◽  
Zagreb Index ◽  
Storage Devices ◽  
Metal Organic

AbstractMetal-organic frameworks (MOFs) are porous materials formed by strong bonds between metal ions and organic ligands to represent very high surface area, large pore volume, excellent chemical stability and unique morphology. Work on synthesis, structures and characteristics of many MOFs shows the importance of these frameworks with versatile applications, such as energy storage devices of excellent electrode materials, gas storage, heterogeneous catalysis, environmental hazard, assessment of chemicals and sensing of different gases. A topological property or index is a numerical invariant that predicts the physicochemical properties of the chemical compounds of the underlying molecular graph or framework. Wiener (1947) created the practice of the topological indices (TI’s) in organic molecules with the reference of boiling point of paraffin. In this paper, we study the two different metal-organic frameworks with respect to the number of increasing layers with metal and organic ligands as well. We also compute the generalized Zagreb index and generalized Zagreb connection index of these frameworks. Moreover, the various indices and connection indices are obtained by using the aforesaid generalized versions. At the end, a comparison is also included between the indices and connection indices with the help of numerical values and their 3D plots.

Carbon nanofibers by pyrolysis of self-assembled perylene diimide derivative gels as supercapacitor electrode materials

2015 ◽  
Vol 3 (30) ◽  
pp. 15513-15522 ◽  
Author(s):  
Xia Liu ◽  
Aled Roberts ◽  
Adham Ahmed ◽  
Zhenxin Wang ◽  
Xu Li ◽  
...  
Keyword(s):  
Surface Area ◽  
Carbon Nanofibers ◽  
High Performance ◽  
Electrode Materials ◽  
High Surface ◽  
High Surface Area ◽  
Perylene Diimide ◽  
Supercapacitor Electrode ◽  
Water Based ◽  
Supercapacitor Electrode Materials

A water-based approach to fabricating CNFs from a perylene diimide derivative via gelation and carbonization is described. Pluronic F-127 as templates can be readily incorporated to form CNFs with high surface area, showing high performance as electrode materials for supercapacitors.

From ZIF nanoparticles to hierarchically porous carbon: toward very high surface area and high-performance supercapacitor electrode materials

2019 ◽  
Vol 6 (1) ◽  
pp. 32-39 ◽  
Author(s):  
Fangfang Wang ◽  
Liangkui Zhu ◽  
Ying Pan ◽  
Zhan Li ◽  
Pingping Yang ◽  
...  
Keyword(s):  
Surface Area ◽  
High Performance ◽  
Electrode Materials ◽  
High Surface ◽  
High Surface Area ◽  
High Specific Capacitance ◽  
Supercapacitor Electrode ◽  
Capacitive Energy Storage ◽  
Energy Storage Material ◽  
Supercapacitor Electrode Materials

A high-performance capacitive energy storage material was derived from a new nanoscale ZIF precursor by using the activating reagent KOH, exhibiting a high surface area of 3253 m2 g−1 and an ultra-high specific capacitance.

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