17.25% High Efficiency Ternary Solar Cells with Increased Open-Circuit Voltage by a High HOMO Level Small Molecular Guest Donor in a PM6:Y6 Blend

Author(s):  
Wei Tang ◽  
Wenhong Peng ◽  
Mengbing Zhu ◽  
Huanxiang Jiang ◽  
Wenchao Wang ◽  
...  

A small molecular donor TiC12 with asymmetric thieno[3,2-c]isochromene unit is incorporated into the PM6:Y6 system as the third component for constructing ternary organic solar cells (OSCs). It was found that...

RSC Advances ◽  
2019 ◽  
Vol 9 (36) ◽  
pp. 20733-20741 ◽  
Author(s):  
HyunKyung Lee ◽  
Sora Oh ◽  
Chang Eun Song ◽  
Hang Ken Lee ◽  
Sang Kyu Lee ◽  
...  

A 3D-shaped SF-HR was designed and synthesized for use in non-fullerene organic solar cells. Owing to the aligned energy levels, the P3HT:SF-HR system exhibited a high efficiency of 4.01% with good thermal stability and photostability.


2015 ◽  
Vol 3 (9) ◽  
pp. 1904-1912 ◽  
Author(s):  
Yu Jin Kim ◽  
Ye Rim Cheon ◽  
Jae-Wan Jang ◽  
Yun-Hi Kim ◽  
Chan Eon Park

We designed a new copolymer, PNDT-BTN with NDT and alkoxy-naphthalene units. PNDT-BDT showed an effectively lowered HOMO level by inducing non-planarity, resulting in enhanced VOC.


2020 ◽  
Vol 22 (7) ◽  
pp. 4015-4022 ◽  
Author(s):  
Li-Na Wu ◽  
Ming-Yue Sui ◽  
Song Xiao ◽  
Yu-Zhong Xie ◽  
Guang-Yan Sun

The energy level gradient-distribution screening strategy of fragments is an effective way to reduce the HOMO level and increase VOC.


2018 ◽  
Vol 1 ◽  
pp. 47-59 ◽  
Author(s):  
Bin Yang ◽  
Junchi Li ◽  
Chuanguang Wu ◽  
Hao Zhang ◽  
Anlian Pan ◽  
...  

2019 ◽  
Vol 7 (48) ◽  
pp. 27394-27402 ◽  
Author(s):  
Hui Guo ◽  
Youdi Zhang ◽  
Lie Chen ◽  
Xunfan Liao ◽  
Qian Xie ◽  
...  

The difluorine and carboxylate substitutions can effectively down-shift the HOMO level of the donors, improved molecular face-on orientation and reduced energy loss.


2019 ◽  
Vol 115 (15) ◽  
pp. 153301 ◽  
Author(s):  
Seiichiro Izawa ◽  
Naoto Shintaku ◽  
Mitsuru Kikuchi ◽  
Masahiro Hiramoto

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 592
Author(s):  
Myeong Sang Jeong ◽  
Yonghwan Lee ◽  
Ka-Hyun Kim ◽  
Sungjin Choi ◽  
Min Gu Kang ◽  
...  

In the fabrication of crystalline silicon solar cells, the contact properties between the front metal electrode and silicon are one of the most important parameters for achieving high-efficiency, as it is an integral element in the formation of solar cell electrodes. This entails an increase in the surface recombination velocity and a drop in the open-circuit voltage of the solar cell; hence, controlling the recombination velocity at the metal-silicon interface becomes a critical factor in the process. In this study, the distribution of Ag crystallites formed on the silicon-metal interface, the surface recombination velocity in the silicon-metal interface and the resulting changes in the performance of the Passivated Emitter and Rear Contact (PERC) solar cells were analyzed by controlling the firing temperature. The Ag crystallite distribution gradually increased corresponding to a firing temperature increase from 850 ∘C to 950 ∘C. The surface recombination velocity at the silicon-metal interface increased from 353 to 599 cm/s and the open-circuit voltage of the PERC solar cell decreased from 659.7 to 647 mV. Technology Computer-Aided Design (TCAD) simulation was used for detailed analysis on the effect of the surface recombination velocity at the silicon-metal interface on the PERC solar cell performance. Simulations showed that the increase in the distribution of Ag crystallites and surface recombination velocity at the silicon-metal interface played an important role in the decrease of open-circuit voltage of the PERC solar cell at temperatures of 850–900 ∘C, whereas the damage caused by the emitter over fire was determined as the main cause of the voltage drop at 950 ∘C. These results are expected to serve as a steppingstone for further research on improvement in the silicon-metal interface properties of silicon-based solar cells and investigation on high-efficiency solar cells.


RSC Advances ◽  
2015 ◽  
Vol 5 (79) ◽  
pp. 64724-64730 ◽  
Author(s):  
Derya Baran ◽  
Sule Erten-Ela ◽  
Andreas Kratzer ◽  
Tayebeh Ameri ◽  
Christoph J. Brabec ◽  
...  

In this work, a bis-adduct C60 derivative was facilely synthesized using an alkyl solubilizing group. This semiconductor offers a higher LUMO level compared to PCBM, which resulted in a significantly enhanced Voc of 0.73 V in organic solar cells.


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