Performance and Stability Improvements in Metal Halide Perovskite with Intralayer Incorporation of Organic Additives

Author(s):  
Yanan Li ◽  
Matthew Dailey ◽  
Patrick Lohr ◽  
Adam Printz

Metal halide perovskites are emerging semiconducting materials with a wide range of applications, including photovoltaics, thin-film transistors, and light-emitting diodes. A key advantage of perovskites over more established semiconductor technologies...

2021 ◽  
Vol 97 ◽  
pp. 417-425
Author(s):  
Bong Woo Kim ◽  
Jin Hyuck Heo ◽  
Jin Kyoung Park ◽  
David Sunghwan Lee ◽  
Hyunik Park ◽  
...  

Author(s):  
Oluwaseun Victor Romiluyi ◽  
Yannick Eatmon ◽  
Ruihao Ni ◽  
Barry P. Rand ◽  
Paulette Clancy

Solvents employed in the solution processing of metal halide perovskites are known to play a key role in defining the morphology and properties of the resulting thin film, and thus...


Author(s):  
Kyung-Geun Lim ◽  
Tae-Hee Han ◽  
Tae-Woo Lee

Organic-inorganic hybrid metal halide perovskites have excellent optoelectronic properties and are soft and resilient; therefore, they are appropriate for use in flexible and stretchable electronic devices. Commercialization of these perovskite...


2019 ◽  
Vol 68 (15) ◽  
pp. 158505
Author(s):  
Zhen-Chao Li ◽  
Zi-Ming Chen ◽  
Guang-Rui-Xing Zou ◽  
Hin-Lap Yip ◽  
Yong Cao

2021 ◽  
Vol 22 ◽  
pp. 100946
Author(s):  
Le Ma ◽  
Boning Han ◽  
Fengjuan Zhang ◽  
Leimeng Xu ◽  
Tao Fang ◽  
...  

Author(s):  
Wenjing Feng ◽  
Kebin Lin ◽  
Wenqiang Li ◽  
Xiangtian Xiao ◽  
Jianxun Lu ◽  
...  

Metal halide perovskite light-emitting diodes (PeLEDs) are promising in lighting and display application, and the corresponding device performance is highly dependent on the film quality of the active layer. However,...


Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Zhifang Tan ◽  
Jincong Pang ◽  
Guangda Niu ◽  
Jun-Hui Yuan ◽  
Kan-Hao Xue ◽  
...  

Abstract Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal halide scintillators (NaI: Tl, LaBr3, etc.) are also severely restricted by their high hygroscopicity. Here we report a new kind of lead free perovskite with excellent water and radiation stability, Rb2Sn1-x Te x Cl6. The equivalent doping of Te could break the in-phase bonding interaction between neighboring octahedra in Rb2SnCl6, and thus decrease the electron and hole dimensionality. The optimized Te content of 5% resulted in high photoluminescence quantum yield of 92.4%, and low X-ray detection limit of 0.7 µGyair s−1. The photoluminescence and radioluminescence could be maintained without any loss when immersing in water or after 480,000 Gy radiations, outperforming previous perovskite and traditional metal halides scintillators.


Small Science ◽  
2021 ◽  
Vol 1 (8) ◽  
pp. 2170020
Author(s):  
Michael Worku ◽  
Azza Ben-Akacha ◽  
Tunde Blessed Shonde ◽  
He Liu ◽  
Biwu Ma

2020 ◽  
Vol 6 (17) ◽  
pp. eaaz5961 ◽  
Author(s):  
Michael Worku ◽  
Yu Tian ◽  
Chenkun Zhou ◽  
Haoran Lin ◽  
Maya Chaaban ◽  
...  

Metal halide perovskite nanocrystals (NCs) have emerged as new-generation light-emitting materials with narrow emissions and high photoluminescence quantum efficiencies (PLQEs). Various types of perovskite NCs, e.g., platelets, wires, and cubes, have been discovered to exhibit tunable emissions across the whole visible spectrum. Despite remarkable advances in the field of perovskite NCs, many nanostructures in inorganic NCs have not yet been realized in metal halide perovskites, and producing highly efficient blue-emitting perovskite NCs remains challenging and of great interest. Here, we report the discovery of highly efficient blue-emitting cesium lead bromide (CsPbBr3) perovskite hollow NCs. By facile solution processing of CsPbBr3 precursor solution containing ethylenediammonium bromide and sodium bromide, in situ formation of hollow CsPbBr3 NCs with controlled particle and pore sizes is realized. Synthetic control of hollow nanostructures with quantum confinement effect results in color tuning of CsPbBr3 NCs from green to blue, with high PLQEs of up to 81%.


Sign in / Sign up

Export Citation Format

Share Document