Towards Superior X-ray Detection Performance of Two-dimensional Halide Perovskite Crystals by Adjusting Anisotropic Transport Behavior

2021 ◽  
Author(s):  
Bao Xiao ◽  
Qihao Sun ◽  
Fangbao Wang ◽  
Shiyao Wang ◽  
Binbin Zhang ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Detection Performance ◽  
Two Dimensional ◽  
Inorganic Hybrid ◽  
X Ray ◽  
Transport Behavior ◽  
Halide Perovskites ◽  
Anisotropic Transport ◽  
Halide Perovskite ◽  
Optoelectronic Applications

Two-dimensional (2D) organic-inorganic hybrid halide perovskites have recently attracted extensive attention for electronic and optoelectronic applications due to their tunable properties and superior stability compared with their three-dimensional (3D) counterparts....

scholarly journals Nanometer-Thick [(FPEA)2PbX4; X=I, Br] 2D Halide Perovskite Based Thin Films for Pollutant Detection and Nonconventional Photocatalytic Degradation

2021 ◽  
Author(s):  
Arindam Mondal ◽  
Akash Lata ◽  
Aarya Prabhakaran ◽  
Satyajit Gupta
Keyword(s):  
Thin Films ◽  
Photocatalytic Degradation ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Reduced Dimensionality ◽  
P Application ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Pollutant Detection

Application of three-dimensional (3D)-halide perovskites (HaP) in photocatalysis encourages the new exercise with two-dimensional (2D) HaP based thin-films for photocatalytic degradation of dye. The reduced dimensionality to 2D-HaPs, with a...

Exploring the Ruddlesden−Popper Layered Organic-Inorganic Hybrid Semiconducting Perovskite for Visible-Blind Ultraviolet Photodetection

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yuyin Wang ◽  
Bin Su ◽  
Guoming Lin ◽  
Huiru Lou ◽  
Shouxin Wang ◽  
...  
Keyword(s):  
Physical Properties ◽  
Three Dimensional ◽  
Metal Halide ◽  
Two Dimensional ◽  
Inorganic Hybrid ◽  
Perovskite Materials ◽  
Halide Perovskites ◽  
P Type ◽  
Visible Blind

Compared to the three-dimensional (3D) perovskite materials, the Ruddlesden−Popper (R-P) type two-dimensional (2D) organic-inorganic metal halide perovskites have indicated specific unique physical properties that include moisture-stable behaviours, exciton effects, and...

Two Nickel-Bipyridinedicarboxylate Organic-Inorganic Hybrid Materials: Hydrothermal Synthesis, Crystal Structure and Thermal Properties

2010 ◽  
Vol 152-153 ◽  
pp. 144-148
Author(s):  
Yan Xia Song ◽  
Chong Chen Wang ◽  
Yuan Lan Wang
Keyword(s):  
Thermogravimetric Analysis ◽  
Dicarboxylic Acid ◽  
Hydrothermal Reaction ◽  
Three Dimensional ◽  
Tridentate Ligand ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Inorganic Hybrid ◽  
X Ray ◽  
Hydrogen Bonding Interactions

Two two-dimensional and three-dimensional coordination-polymer, [Ni(2,2′,5,5′-bpdc) (H2O)]•H2O (1) and[Ni(2,2′,6,6′-bpdc)2]•4H2O (2) were obtained via hydrothermal reaction between NiCl2•6H2O and 2,2′-bipyridine-5,5′-dicarboxylic acid (2,2′,5,5′-bpdc), 2,2′-bipyridine-6,6′-dicarboxylic acid (2,2′,6,6′-bpdc) respectively, and were characterized by infrared spectra, thermogravimetric analysis and single crystal X-ray diffraction. The 2,2′,5,5′-bpdc and 2,2′,6,6′-bpdc ligands in compound 1 and 2 show different coordination modes respectively. The 2,2′,5,5′-bpdc ligand acts as pentadentate connector to coordinate with three different Ni(II) ions, and further extend to form square grid framework of compound 1; while 2,2′,6,6′-bpdc acts as tridentate ligand to chelate one Ni(II) ion to construct discrete monomeric unit, and those discrete units of [Ni(2,2′6,6′-bpdc)2]•4H2O are joined into 3-D framework via rich hydrogen bonding interactions. Thermogravimetric analysis revealed that both complex (1) and (2) display considerable thermal stability. CCDC 773845 & 773846.

Two New Three-Dimensional Networks Constructed on Polyoxovanadates

2007 ◽  
Vol 60 (11) ◽  
pp. 871 ◽  
Author(s):  
Yan-fei Qi ◽  
Dongrong Xiao ◽  
Enbo Wang ◽  
Zhiming Zhang ◽  
Xinlong Wang
Keyword(s):  
Thermogravimetric Analysis ◽  
Rare Case ◽  
Three Dimensional ◽  
Network Connectivity ◽  
Two Dimensional ◽  
Crystal Data ◽  
X Ray Diffraction ◽  
Inorganic Hybrid ◽  
X Ray

To investigate the role of polyoxovanadates in network connectivity, two new organic–inorganic hybrid vanadates with three-dimensional entangled coordination frameworks, namely [Cu2(biim)3V4O12] 1 and [Co2(biim)3V4O12]·4H2O 2 have been synthesized and characterized by infrared (IR), thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. Crystal data for compound 1: triclinic, P-1, a 9.504(2), b 10.650(2), c 11.993(2) Å; α 72.13(3), β 76.02(3), γ 65.40(3)°; V 1041.4(4) Å3, Z 2, R(final) 0.0492. Crystal data for compound 2: triclinic, P-1, a 9.037(3), b 10.577(2), c 11.9470(2) Å; α 87.80(3), β 81.71(3), γ 85.29(3)°; V 1125.8(4) Å3, Z 1, R(final) 0.0774. Compound 1 is a three-dimensional inclined hetero-catenated framework designed from two two-dimensional sub-layers, [Cu(biim)V4O12] and [Cu(biim)2]. Compound 2 is a rare case of a self-catenated ‘ilc’ network that displays an unusual 424·5·63 topology with the binuclear {Co2O4N6} units as eight-connected nodes.

scholarly journals Design two-dimensional halide perovskite composites for optoelectronic applications and beyond

2021 ◽  
Author(s):  
Tao Song ◽  
Qing-xiu Ma ◽  
Qiang Wang ◽  
Hao-Li Zhang
Keyword(s):  
Electronic Properties ◽  
Two Dimensional ◽  
Information Display ◽  
Optical And Electronic Properties ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Optoelectronic Applications ◽  
Energy Information

Two-dimensional (2D) halide perovskites have attracted ever-increasing attention because of their unique optical and electronic properties that result into versatile applications in the fields of energy, information, display and lighting,...

scholarly journals Tailoring the electron and hole dimensionality to achieve efficient and stable metal halide perovskite scintillators

Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Zhifang Tan ◽  
Jincong Pang ◽  
Guangda Niu ◽  
Jun-Hui Yuan ◽  
Kan-Hao Xue ◽  
...  
Keyword(s):  
Water Solubility ◽  
Radiation Stability ◽  
Metal Halide ◽  
Lead Free ◽  
X Ray ◽  
Metal Halide Perovskite ◽  
Bonding Interaction ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Low X

Abstract Metal halide perovskites have recently been reported as excellent scintillators for X-ray detection. However, perovskite based scintillators are susceptible to moisture and oxygen atmosphere, such as the water solubility of CsPbBr3, and oxidation vulnerability of Sn2+, Cu+. The traditional metal halide scintillators (NaI: Tl, LaBr3, etc.) are also severely restricted by their high hygroscopicity. Here we report a new kind of lead free perovskite with excellent water and radiation stability, Rb2Sn1-x Te x Cl6. The equivalent doping of Te could break the in-phase bonding interaction between neighboring octahedra in Rb2SnCl6, and thus decrease the electron and hole dimensionality. The optimized Te content of 5% resulted in high photoluminescence quantum yield of 92.4%, and low X-ray detection limit of 0.7 µGyair s−1. The photoluminescence and radioluminescence could be maintained without any loss when immersing in water or after 480,000 Gy radiations, outperforming previous perovskite and traditional metal halides scintillators.

scholarly journals Low-Zpolymer sample supports for fixed-target serial femtosecond X-ray crystallography

2015 ◽  
Vol 48 (4) ◽  
pp. 1072-1079 ◽  
Author(s):  
Geoffrey K. Feld ◽  
Michael Heymann ◽  
W. Henry Benner ◽  
Tommaso Pardini ◽  
Ching-Ju Tsai ◽  
...  
Keyword(s):  
Protective Antigen ◽  
Three Dimensional ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Fixed Target ◽  
X Ray ◽  
X Ray Crystallography ◽  
Transmission Electron ◽  
Linac Coherent Light Source ◽  
Efficient Alternative

X-ray free-electron lasers (XFELs) offer a new avenue to the structural probing of complex materials, including biomolecules. Delivery of precious sample to the XFEL beam is a key consideration, as the sample of interest must be serially replaced after each destructive pulse. The fixed-target approach to sample delivery involves depositing samples on a thin-film support and subsequent serial introductionviaa translating stage. Some classes of biological materials, including two-dimensional protein crystals, must be introduced on fixed-target supports, as they require a flat surface to prevent sample wrinkling. A series of wafer and transmission electron microscopy (TEM)-style grid supports constructed of low-Zplastic have been custom-designed and produced. Aluminium TEM grid holders were engineered, capable of delivering up to 20 different conventional or plastic TEM grids using fixed-target stages available at the Linac Coherent Light Source (LCLS). As proof-of-principle, X-ray diffraction has been demonstrated from two-dimensional crystals of bacteriorhodopsin and three-dimensional crystals of anthrax toxin protective antigen mounted on these supports at the LCLS. The benefits and limitations of these low-Zfixed-target supports are discussed; it is the authors' belief that they represent a viable and efficient alternative to previously reported fixed-target supports for conducting diffraction studies with XFELs.

Stable Formamidinium‐Based Centimeter Long Two‐Dimensional Lead Halide Perovskite Single‐Crystal for Long‐Live Optoelectronic Applications

2021 ◽  
pp. 2112277
Author(s):  
Rajesh Kumar Ulaganathan ◽  
Raghavan Chinnambedu Murugesan ◽  
Chang‐Yu Lin ◽  
Ambika Subramanian ◽  
Wei‐Liang Chen ◽  
...  
Keyword(s):  
Single Crystal ◽  
Two Dimensional ◽  
Halide Perovskite ◽  
Optoelectronic Applications ◽  
Lead Halide

scholarly journals Advances in two-dimensional organic–inorganic hybrid perovskites

2020 ◽  
Vol 13 (4) ◽  
pp. 1154-1186 ◽  
Author(s):  
Fei Zhang ◽  
Haipeng Lu ◽  
Jinhui Tong ◽  
Joseph J. Berry ◽  
Matthew C. Beard ◽  
...  
Keyword(s):  
Two Dimensional ◽  
Inorganic Hybrid ◽  
Basic Properties ◽  
Optoelectronic Applications

Recent achievements of 2D perovskites for various optoelectronic applications along with their basic properties and future opportunities are discussed.

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