Revealing Effect of Interfacial Electron Transfer in Heterostructured Co9S8@NiFe LDH for Enhanced Electrocatalytic Oxygen Evolution

Author(s):  
Xueting Feng ◽  
Qingze Jiao ◽  
Zheng Dai ◽  
Yanliu Dang ◽  
Steven L Suib ◽  
...  

Heterointerface engineering is a desirable way to rationally design efficient and low-cost electrocatalysts for the oxygen evolution reaction (OER). Herein, the urchin-like Co9S8@NiFe layered double hydroxide (Co9S8@NiFe LDH) heterostructured hollow...

Catalysts ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 431
Author(s):  
Haitong He ◽  
Jun Gu ◽  
Xiaomeng Liu ◽  
Delong Yang ◽  
Yong Zhu ◽  
...  

The pursuit of highly active and cost-effective catalysts toward oxygen evolution reaction (OER) is a crucial strategy to resolve the imminent energy crisis. NiFe layered double hydroxide (NiFe LDH) is acknowledged as one of the most promising OER electrocatalysts in alkaline electrolytes. Herein, we report a novel stepwise approach to synthesize NiFe LDHs materials merging with carbon black (CB) via trisodium citrate (TC), modifying toward OER. Benefiting from the inimitable wrapped structure, the decreased size of porous nanosheets and the superconductivity of CB substrate, NiFe LDHs/CB-TC presents excellent catalytic features with a comparative overpotential (236 mV at 10 mA cm−2) and an ultralow Tafel slope (31 mV dec−1), which are almost lower than those of advanced catalysts associated with expensive carbonaceous materials. Therefore, it is expected that such a high-activity and low-cost material can be a promising catalyst employed for the electrochemical energy storage and conversion systems.


2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...


CrystEngComm ◽  
2022 ◽  
Author(s):  
Meng Ya Yang ◽  
Rong Zhao ◽  
Yi Liu ◽  
Hua Lin

In this work, high efficient electrocatalyst Fe-Ni2P/N-GO with hierarchical structure was developed through phosphating NiFe-based layered double hydroxide (LDH) supported by N-doped graphene oxide (GO), which was assembled by the...


2018 ◽  
Vol 6 (7) ◽  
pp. 3224-3230 ◽  
Author(s):  
Li-Ming Cao ◽  
Jia-Wei Wang ◽  
Di-Chang Zhong ◽  
Tong-Bu Lu

The development of readily available, highly efficient and stable electrocatalysts for the oxygen evolution reaction (OER) is extremely significant to facilitate water splitting for the generation of clean hydrogen energy.


2020 ◽  
Vol 44 (24) ◽  
pp. 9981-9997 ◽  
Author(s):  
Josué M. Gonçalves ◽  
Paulo R. Martins ◽  
Lucio Angnes ◽  
Koiti Araki

The recent advances in ternary layered double hydroxide electrocatalysts, including the strategies used for the design, synthesis, and evaluation of their performance for oxygen evolution reaction are reviewed in this account.


2018 ◽  
Vol 47 (48) ◽  
pp. 17342-17348 ◽  
Author(s):  
Euiyoung Jung ◽  
Jae Kyeom Kim ◽  
Hyungsuk Choi ◽  
Min Hyung Lee ◽  
Taekyung Yu

Transition metal LDH nanoplates were synthesized by heating an aqueous solution containing a metal salt, PEG, and octylamine. The LDH nanoplates showed comparable electrochemical catalytic performance for the oxygen evolution reaction.


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